Electrophilic Displacement Reactions. X. General Acid Catalysis in the Protodeboronation of Areneboronic Acids1-3

HG Kuivila, KV Nahabedian - Journal of the American Chemical …, 1961 - ACS Publications
The kinetics of the protodeboronation of j7-methoxybenzeneboronic acid in aqueous
sulfuric, phosphoric and perchloric acids, and informic acid havebeen studied. The rate …

Electrophilic Displacement Reactions. XII. Substituent Effects in the Protodeboronation of Areneboronic Acids1-3

KV Nahabedian, HG Kuivila - Journal of the American Chemical …, 1961 - ACS Publications
Kinetic studies on the hydrolysis of nine areneboronic acids in aqueous sulfuric and
phosphoric acids are described. Dependence of rate on acidity has been examined in each …

Electrophilic Displacement Reactions. XVI. Metal Ion Catalysis in the Protodeboronation of Areneboronic Acids1-3

HG Kuivila, JF Reuwer… - Journal of the American …, 1964 - ACS Publications
A kinetic investigation has been made of the protodeboronation of benzeneboronic acids,
and the effects of pH andof substituents in the o-, m-, and^-positions on rate. The pH-rate …

Electrophilic displacement reactions: XV. Kinetics and mechanism of the base-catalyzed protodeboronation of areneboronic acids

HG Kuivila, JF Reuwer Jr… - Canadian journal of …, 1963 - cdnsciencepub.com
An investigation of the kinetics of the protodeboronation of benzeneboronic acid in water in
the pH range 2.0 to 6.7 is described. In addition to the acid-catalyzed reaction studied earlier …

Electrophilic Displacement Reactions. XI. Solvent Isotope Effects in the Protodeboronation of Areneboronic Acids1-3

HG Kuivila, KV Nahabedian - Journal of the American Chemical …, 1961 - ACS Publications
Results The effect of solvent hydrogen isotope composi-tion on the rate of
protodeboronation of p-meth-oxybenzeneboronic acid in 6.31 M sulfuric acid at 25 was …

Electrophilic Displacement Reactions. II. Rates of Brominolysis of Substituted Benzeneboronic Acids1,2

HG Kuivila, AR Hendrickson - Journal of the American Chemical …, 1952 - ACS Publications
The results indicate that molecular bromine attacks a quadricovalent boron intermediate in
the rate-determining step. The present paper describes an extension of this work to a study …

Electrophilic Displacement Reactions. III. Kinetics of the Reaction between Hydrogen Peroxide and Benzeneboronic Acid1

HG Kuivila - Journal of the American Chemical Society, 1954 - ACS Publications
A study of the kinetics of the reaction between hydrogen peroxide and benzeneboronic acid
at values ofpH between 2 and 6 has been made. Two ionic mechanisms are distinguishable; …

Electrophilic Displacement Reactions. VII. Catalysis by Chelating Agents in the Reaction between Hydrogen Peroxide and Benzeneboronic Acid1,2,3

HG Kuivila, RA Wiles - Journal of the American Chemical Society, 1955 - ACS Publications
Nineteen chelating agents have been tested for catalytic activity on the reaction between
benzeneboronic acid and hydro-gen peroxide. Free oxalic and malonic acids have no effect …

Electrophilic Displacement Reactions. IX. Effects of Substituents on Rates of Reactions between Hydrogen Peroxide and Benzeneboronic Acid1-3

HG Kuivila, AG Armour - Journal of the American Chemical …, 1957 - ACS Publications
The effects of meta and para substituents on the rates of reactions between benzeneboronic
acid and hydrogen peroxide have been measured. Ten substituents and five different …

Organoboron Compounds, and the Study of Reaction Mechanisms. Primary Aliphatic Boronic Acids1

HR Snyder, JA Kuck, JR Johnson - Journal of the American …, 1938 - ACS Publications
In the development of current electronic theo-ries of organic reactions, molecules are
considered to react by virtue of a constitutional affinity either for electrons or for atomicnuclei …