Electrophilic Displacement Reactions. XII. Substituent Effects in the Protodeboronation of Areneboronic Acids1-3

KV Nahabedian, HG Kuivila - Journal of the American Chemical …, 1961 - ACS Publications
Kinetic studies on the hydrolysis of nine areneboronic acids in aqueous sulfuric and
phosphoric acids are described. Dependence of rate on acidity has been examined in each …

Electrophilic Displacement Reactions. XI. Solvent Isotope Effects in the Protodeboronation of Areneboronic Acids1-3

HG Kuivila, KV Nahabedian - Journal of the American Chemical …, 1961 - ACS Publications
Results The effect of solvent hydrogen isotope composi-tion on the rate of
protodeboronation of p-meth-oxybenzeneboronic acid in 6.31 M sulfuric acid at 25 was …

Electrophilic Displacement Reactions. X. General Acid Catalysis in the Protodeboronation of Areneboronic Acids1-3

HG Kuivila, KV Nahabedian - Journal of the American Chemical …, 1961 - ACS Publications
The kinetics of the protodeboronation of j7-methoxybenzeneboronic acid in aqueous
sulfuric, phosphoric and perchloric acids, and informic acid havebeen studied. The rate …

Electrophilic displacement reactions: XV. Kinetics and mechanism of the base-catalyzed protodeboronation of areneboronic acids

HG Kuivila, JF Reuwer Jr… - Canadian journal of …, 1963 - cdnsciencepub.com
An investigation of the kinetics of the protodeboronation of benzeneboronic acid in water in
the pH range 2.0 to 6.7 is described. In addition to the acid-catalyzed reaction studied earlier …

Electrophilic Displacement Reactions. XVI. Metal Ion Catalysis in the Protodeboronation of Areneboronic Acids1-3

HG Kuivila, JF Reuwer… - Journal of the American …, 1964 - ACS Publications
A kinetic investigation has been made of the protodeboronation of benzeneboronic acids,
and the effects of pH andof substituents in the o-, m-, and^-positions on rate. The pH-rate …

Electrophilic Displacement Reactions. VIII. 1 Rates of Brominolysis of Substituted Benzeneboronic Acids. Correlation of Rates of Aromatic Electrophilic Displacement …

HG Kuivila, LE Benjamin - Journal of the American Chemical …, 1955 - ACS Publications
(3) Substantial support of this investigation by the Officeof Naval Research is gratefully
acknowledged.(4) HG Kuivila and AR Hendrickson, Tina Journal, 74, 5068 i1952) titative …

Electrophilic Displacement Reactions. V. Kinetics of the Iodinolysis of p-Methoxybenzeneboronic Acid1-3

HG Kuivila, RM Williams - Journal of the American Chemical …, 1954 - ACS Publications
The rate of the reaction between iodine and£-methoxybenzeneboronic acid is proportional
to the product of the concentra-tions of the reactants if iodide ion and hydrogen ion …

Electrophilic Displacement Reactions. II. Rates of Brominolysis of Substituted Benzeneboronic Acids1,2

HG Kuivila, AR Hendrickson - Journal of the American Chemical …, 1952 - ACS Publications
The results indicate that molecular bromine attacks a quadricovalent boron intermediate in
the rate-determining step. The present paper describes an extension of this work to a study …

Kinetics of the Brominolysis of Benzeneboronic Acid in Aqueous Acetic Acid Solution

HG Kuivila, EK Easterbrook - Journal of the American Chemical …, 1951 - ACS Publications
The kinetics of the brominolysis of benzeneboronic acid in aqueous acetic acid solution
have been investigated. The re-action is first order in bromine and in benzeneboronic acid …

Electrophilic Displacement Reactions. XIII. the Kinetics of the Phenylmercurideboronation of Benzeneboronic Acid1-3

HG Kuivila, TC Muller - Journal of the American Chemical Society, 1962 - ACS Publications
The kinetics of the reaction between benzeneboronic acid andbasic phenylmercuric
perchlorate in aqueous ethanol have been studied. The rate was found to be first order in …