JP2003012411A - Fungiproof composition - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a safe fungiproof composition having excellent fungiproof and fungicidal effects, and further having satisfactory persistence of the effects. SOLUTION: This fungiproof composition contains (a) a mixture of acylated glycerols containing a monoacyl glycerol in a specific ratio, (b) one or more kinds of perfume components selected from (b-1) specified perfumes and/or (b-2) specified natural essential oils, (c) 1-70 wt.% of an organic compound which forms an azeotrope with water so as to have an azeotropic point with water of <100 deg.C at 1013.25 hPa, and (d) water.

Description

Description: TECHNICAL FIELD [0001] The present invention relates to a fungicide composition. [0002] Since Japan is a hot and humid area, it is in an environment suitable for the growth of mold. For this reason, various places such as indoor and bathroom walls, windows, floors and other buildings, underwear, socks, bath towels and other clothing, shoe boxes, closets and other storage locations, shoe insoles, shoes, floor mats, etc. Mold grows on the surface. In recent years, the housing environment has been shifting to a highly heat-insulated and airtight structure, and the growth of mold has been further promoted. For this reason, it is also a major problem in environmental hygiene, and fungicides and fungicides are being developed. [0003] JP-A-9-286760 discloses that salicylic acid derivatives are excellent as antibacterial and antifungal agents. JP-A-7-179318 discloses a technique for a fungicide using natural hiba oil. JP-A-8-59419 discloses that hinokitiol and citronellic acid are effective against filamentous fungi and Pseudomonas aeruginosa. Japanese Patent Application Laid-Open No. Hei 7-309706 discloses a technology of a spray for germicidal and fungicide using silver. In addition, various compounds such as a benzimidazole compound, a thiabendazole compound, a thiazoline compound, a triazine compound, a phenol ether compound, an alkylamine compound, an organotin compound, and a silver compound have been used. I have. However, many of these have problems in safety, such as acute oral toxicity, skin irritation, and mucous membrane irritation, and those with few safety problems have satisfactory antibacterial effects themselves. It was at a level that could be achieved, or improvement in the sustainability of the effect was desired. Therefore, development of a fungicide / fungicide which is highly safe and has a satisfactory effect for a long time is desired. On the other hand, monoglycerides known as food additives are known to exhibit resistance to bacteria. JP-A-2-180804 discloses an antibacterial agent containing bamboo extract and monoglyceride. JP-A-11-61697 uses glycerin fatty acid ester as an emulsifier for bamboo extract. Although these techniques are highly safe in that they use glyceride and natural bamboo extract, they are not satisfactory in terms of fungicidal and fungicidal effects. [0005] Accordingly, an object of the present invention is to provide a fungicide which is excellent in fungicidal and fungicidal effects and can be used with satisfactory sustainability by using a raw material having good safety. The present invention provides a mixture of (a) an acylated glycerol having 6 to 18 carbon atoms in an acyl group, wherein a monoacylated glycerol contains 4% in the mixture.
0.005 to 5% by mass of an acylated glycerol mixture [hereinafter, referred to as “component (a)”] which is 0 to 99.9% by mass;
(B) The following fragrance (b-1) [hereinafter referred to as (b-1) component] and / or natural essential oil (b-2) [hereinafter referred to as (b-
2) a perfume component (hereinafter, referred to as a component (b)) selected from the group consisting of 0.005 to 5% by mass;
(C) forming an azeotrope with water, 1013.25 hPa
A fungicide containing 1 to 70% by mass of an organic compound [hereafter referred to as component (c)] having an azeotropic temperature with water of less than 100 ° C, and (d) water [hereinafter referred to as component (d)]. Agent composition. (B-1) cinamic aldehyde, chavicol, hexanal, heliotropin, methyl eugenol, p
-Isopropylcyclohexanol, acetophenone,
Isoeugenol, undecanal, ethyl caproate, eugenol, octanol, carvacrol, geraniol, cyclamenaldehyde, cedrol, terpinyl acetate, terpinen, thymol, decanol, phenylacetaldehyde, benzyl acetate,
Perilaldehyde, methyl salicylate, linalyl acetate, linalool, limonene, γ-undecalactone, citral, citronellal, citronellol, nerol, hinokitiol, cinnamic alcohol, l
-Carvone, 1-menthol, terpineol, terpinen-4-ol, camphor, borneol, anisaldehyde, vanillin, ethyl vanillin, α-hexylcinnamic aldehyde, octanal, nonanal,
Decanal, anethole, allyl isothiocyanate (b-2) cumin oil, coriander oil, perilla oil, geranium oil, fennel oil, lavender oil, lemongrass oil, rose oil, laurel oil, origanum oil, orange oil, cassia oil, clove Oil, citronella oil, cinnamon oil, sage oil, thyme oil, dill oil,
Tree moss oil, Hiba oil, Pimento oil, Bay oil, Vetiver oil, Penny royal oil, Peruvian balsam oil, Eucalyptus oil, Lemon oil, Rosemary oil, Tea tree oil, Anise oil, Star anise oil, Palmarosa oil, Peppermint oil, Spearmint oil , Basil oil, hinoki oil, lavandin oil, wasabi oil. [0007] In the present invention, the term "mold prevention" includes not only the effect of preventing the occurrence of mold, but also the so-called fungicidal effect of stopping and suppressing the growth of the generated mold and killing it. Therefore, the fungicide composition of the present invention can also be used as a fungicide. DETAILED DESCRIPTION OF THE INVENTION Component (a) Component (a) used in the present invention has an acyl group having 6 to 1 carbon atoms.
8, preferably a mixture of 8 to 14, particularly preferably 8 to 12, acylated glycerol, wherein the proportion of monoacylated glycerol is 40 to 99.9% by weight in the mixture;
Preferably 50 to 99.5% by weight, particularly preferably 60% by weight.
-99.5% by mass of an acylated glycerol mixture. The acylated glycerol can be obtained by a method of synthesizing glycerin with a fatty acid or a lower alcohol ester of a fatty acid by esterification or transesterification, or a method of synthesizing a natural oil or fat with glycerin by transesterification. The acylated glycerol obtained by these reactions is monoacylated glycerol (M
G), a mixture of diacylated glycerol (DG) and triacylated glycerol (TG). Generally, the ratio of MG, DG, and TG of the acylated glycerol obtained in the above reaction is uniquely determined by the reaction molar ratio of the glycerin skeleton to the acyl group. In the present invention, the reaction is carried out so that the monoacylated glycerol falls within the above range. It is preferable to set the molar ratio. Specifically, the reaction molar ratio of the glycerin skeleton: acyl group is 1: 1 to 100: 1, preferably 1: 1 to 10:
1, especially 1: 1 to 3: 1 is preferred. In addition, MG: D of the acylated glycerol synthesized at such a molar ratio is used.
The preferred mass ratio of G: TG is 50-99.5: 40-
0.5: 10 to 0 is preferred. Further, in the present invention, the mixture obtained by the above reaction can be further purified by a thin film distillation machine or the like to obtain a mixture having a high purity of acylated glycerol. In this case, it is also possible to obtain those having an MG ratio of 99.5% by mass or more. The acyl group of the component (a) of the present invention has 6 to 18 carbon atoms, and may be a single acyl group or a mixed acyl group. In the case of a mixed acyl group, those having an alkyl composition selected from coconut oil, palm oil, palm kernel oil, tallow, and fish oil are preferred, and particularly, an acyl group composition derived from coconut oil or palm kernel oil. What you have is good. Component (b) Of the component (b) of the present invention, component (b-1) includes:
Heliotropin, eugenol, camphor, geraniol, citronellol, citral, thymol, carvacrol, limonene are preferred from the viewpoint of fungicidal and fungicidal effects. As the component (b-2), lavender oil,
Lemongrass oil, palmarosa oil, rosemary oil, sage oil, clove oil, thyme oil, and hiba oil are good in terms of antifungal and fungicidal effects. In the present invention, the component (b-1) and / or (b-
2) The components may be used alone or in combination of two or more. Further, a fragrance component other than the component (b-1) and the component (b-2) (hereinafter, referred to as the component (b-3)) may be used in combination. (B-3) As a component, "Perfume Chemistry" (Ryoichi Akahoshi, Chemical Society of Japan, Industrial Chemistry Series)
Published on September 16, 1983, "Synthetic Flavoring Chemistry and Product Knowledge" (Genji Indo, published March 6, 1996) and "Actual Knowledge of Flavoring and Flavoring" (Mikitaka Nakajima, June 1995)
(Issued on March 21) can be used. As the component (b-3), among these, (1) a terpene alcohol having 10 to 15 carbon atoms, (2) an aromatic alcohol having 7 to 15 carbon atoms, (3)
C8-C17 formate or acetate,
It is preferable to use at least one fragrance selected from the group consisting of (4) hydrocarbons having 10 to 15 carbon atoms and (5) aromatic aldehydes having 7 to 15 carbon atoms. Also,
When the component (b-3) is used, [component (b-1) +
(B-2) component] / (b-3) component is 1/5 to 5
The ratio of 5/1, preferably 1/2 to 5/1, is suitable from the viewpoint of fungicidal and fungicidal effects, and for the purpose of imparting a preferable aroma to the composition. Component (c) The component (c) of the present invention forms an azeotrope with water,
It is an organic compound whose azeotropic temperature with water at 3.25 hPa (760 mmHg) is less than 100 ° C., and is described in “Chemical Handbook Basic Edition II” (3rd revised edition, edited by The Chemical Society of Japan, Maruzen Co., Ltd., June 1984) 147 pages, Table 8
Compounds having an azeotropic temperature of less than 100 ° C, preferably 60 to 90 ° C, from the compounds forming an azeotropic mixture with water described in 43 can be used. Preferred specific examples include ethanol, cyclohexane, cyclohexanol, cyclohexanone, cyclohexane, toluene, 1-butanol, 2-butanol, 1-propanol, 2-propanol, 1-hexanol, hexane, 1-heptanol, 1-pentanol, -Pentanol, and an alcohol compound having 2 to 7 carbon atoms is preferable.
In particular, ethanol, 1-propanol, and 2-propanol are most preferable from the viewpoint of fungicidal and fungicidal effects. The component (b) of the present invention that satisfies the condition of the component (c) is counted as the component (b) and is not treated as the component (c). [Antifungal Composition] The antifungal composition of the present invention preferably comprises the components (a) and (b) and (c)
It is in the form of a solution dissolved in the component and the component (d). The ratio of the component (a) in the fungicide composition of the present invention is 0.00
The content is 5 to 5% by mass, preferably 0.01 to 3% by mass, particularly preferably 0.01 to 1% by mass. The component (b) is 0.005 to 5% by mass, preferably 0.005 to 3% by mass, more preferably 0.01 to 1% by mass, and particularly preferably 0.01 to 0.5% by mass. . Furthermore, the component (c) is 1 to 70% by mass, preferably 5 to 60% by mass, and particularly preferably 15 to 60% by mass. The component (d) which is water is 30 to 99% by mass, preferably 30 to 95% by mass, and particularly preferably 40 to 85% by mass. Preferably, the total of the components (a), (b), (c) and (d) is 95 to 100% by mass, more preferably 98 to 1% by mass.
00 mass% is desirable in order to efficiently obtain a fungicidal / fungicidal effect. Although it is optional in the present invention, it preferably contains glycerin for the purpose of uniformly adhering the fungicide composition of the present invention to an object and effectively acting the same. The content of glycerin in the antifungal composition is preferably 0.0001 to 0.5% by mass, more preferably 0.001% by mass.
1 to 0.1% by mass. In the present invention, it is desirable to contain a bamboo extract and / or a benzoquinone derivative for the purpose of further improving the fungicidal and fungicidal effects. As the bamboo extract, an extract obtained by extracting Moso bamboo with ether described in JP-A-2-180804 can be used, and is preferably 0.001 to 1% by mass, more preferably 0.001% by mass in the fungicide composition of the present invention. Is used in a ratio of 0.01 to 0.5% by mass. Further, as the benzoquinoline derivative, ubiquinone, plastquinone, emperin, rabanone, mesaquinone, methylbenzoquinone, hydroxybenzoquinone, and 2,4-methoxybenzoquinone are preferable. The content of the benzoquinoline derivative is 0.1 ppm to 100 pp in the fungicide composition.
m, preferably 0.5 ppm to 50 ppm. In the present invention, a surfactant other than the component (a) is preferably used in an amount of 0.1 to improve permeability to the object.
0001 to 1% by mass, more preferably 0.001 to 1% by mass
It is preferable to contain 0.5% by mass. Preferred surfactants are nonionic surfactants, anionic surfactants, and cationic surfactants. As the nonionic surfactant, compounds represented by the following general formulas (1) and / or (2) are preferable. R ¹ —O— (R ² O) _a —H (1) wherein R ¹ has 8 to 18 carbon atoms, preferably 10 to 16 carbon atoms.
Wherein R ² has ² carbon atoms
Or 3 alkylene groups, preferably an ethylene group. a represents a number of 3 to 20, preferably 4 to 15, and particularly preferably 5 to 10 as an average number of added moles. R ³ — (OR ⁴ ) _b G _c (2) wherein R ³ is a straight-chain carbon atom having 8 to 16, preferably 10 carbon atoms.
To 16, particularly preferably 10 to 14 alkyl groups, R ⁴
Is an alkylene group having 2 to 4 carbon atoms, preferably an ethylene group or a propylene group, particularly an ethylene group, G is a residue derived from a reducing sugar, b is a number having an average value of 0 to 6, and c is an average value of 1 to 1.
The number is 10, preferably 1 to 5, particularly preferably 1 to 2. ]. Particularly preferred compounds of the general formula (1) include compounds of the following general formula (1-1) and compounds of the general formula (1-2). R ⁵ —O (EO) _d —H (1-1) [wherein, R ⁵ has 10 to 18 carbon atoms, preferably 10 to 1 carbon atoms.
6 primary alkyl groups, branched alkyl groups or secondary alkyl groups. EO is ethylene oxide, and d is 3 to 20 as an average addition mole number. R ⁶ —O [(EO) _e / (PO) _f ] —H (1-2) wherein R ⁶ has 10 to 18 carbon atoms, preferably 10 to 1 carbon atoms.
6 primary alkyl groups. EO indicates ethylene oxide, and PO indicates propylene oxide. e is an average number of added moles of 3 to 15, and f is an average number of added moles of 1 to 5. E
O and PO may be added randomly after adding EO or EO, and then may be added as a block, or vice versa. ]. In the compound of the general formula (2), G
Is a residue derived from a reducing sugar, and the reducing sugar as a raw material may be any of aldose and ketose, and may include triose, tetrose, pentose, and hexose having 3 to 6 carbon atoms. it can. Specific examples of aldose include apiose, arabinose, galactose, glucose, lyxose, mannose, galose, aldose, idose, talose, and xylose, and examples of ketose include fructose. In the present invention, among these, aldopentoses or aldohexoses having 5 or 6 carbon atoms are preferred, and glucose is most preferred. As the anionic surfactants, those having 10 carbon atoms
Alkyl benzene sulfonate, alkenyl succinate, alkyl sulfate, α-olefin sulfonate, α-olefin
Surfactants selected from sulfo fatty acid salts, α-sulfo fatty acid lower alkyl ester salts, fatty acids and fatty acid salts are preferred. As the alkylbenzene sulfonate,
Among those generally distributed in the detergent surfactant market, any one having an alkyl chain having an average carbon number of 8 to 16 can be used. For example, Kao Corporation's Neoperex F25, Shell Dobs 102 manufactured by the company can be used. In addition, industrially, it can also be obtained by sulfonating alkylbenzene, which is widely distributed as a detergent raw material, using an oxidizing agent such as chlorosulfonic acid or sulfurous acid gas. The average carbon number of the alkyl group is 10 to 1
4 is preferred. As the alkyl sulfate salt, a linear or branched primary alcohol or a linear secondary alcohol having 10 to 16 carbon atoms, preferably 10 to 14 carbon atoms, is used.
It can be obtained by sulfonating with ₃ or chlorosulfonic acid and neutralizing. As the α-olefin sulfonate,
A mixture of a compound having a hydroxy group and a compound having an unsaturated bond in a hydrocarbon group, which can be formed by sulfonating an α-alkene having 8 to 18 carbon atoms with SO ₃ and hydration / neutralization. It is. As the α-sulfofatty acid lower alkyl ester salt, the alkyl group has 1 carbon atom.
0-16 are preferable, and a methyl ester or an ethyl ester is preferable from a point of a washing | cleaning effect. In the present invention, alkyl sulfate salts having 10 to 14 carbon atoms are particularly good from the viewpoint of the cleaning effect. As the fatty acid, a saturated fatty acid having 8 to 14 carbon atoms, preferably caprylic acid, capric acid, lauric acid, and myristic acid is preferable. Also, fatty acids having an alkyl distribution derived from coconut oil or palm kernel oil can be used. The salts include sodium, potassium, magnesium, calcium, alkanolamine salts,
Ammonium salts are preferred, and sodium, potassium and magnesium salts are preferred from the viewpoint of the washing effect. As the cationic surfactant, use of compounds represented by the following general formulas (3) to (5) is also preferable from the viewpoint of the deodorizing effect of clothing. Embedded image Wherein R ⁷ and R ¹² are each an alkyl group or alkenyl group having 5 to 16 carbon atoms, preferably 6 to 14 carbon atoms, preferably an alkyl group, and R ⁹ and R ¹⁰ are
Each is an alkyl group having 1 to 3 carbon atoms or a hydroxyalkyl group. T is -COO-, OCO-, -CONH
-, -NHCO-, or Is as follows. g is a number of 0 or 1. R
⁸ is an alkylene group having 1 to 6 carbon atoms, or - (O-R ¹⁷⁾ _n
-. Here, R ¹⁷ is an ethylene group or a propylene group, preferably an ethylene group, and n is 1 to 1
0, preferably a number from 1 to 5. R ¹¹ has 1 to 1 carbon atoms
5, preferably 2 or 3 alkylene groups. Also,
R ¹³ , R ¹⁴ , R ¹⁵ , and R ¹⁶ are two or more (preferably two) of these alkyl groups having 8 to 12 carbon atoms, and the remainder is an alkyl group or hydroxyalkyl group having 1 to 3 carbon atoms. It is. Further, Z ^- is an anionic group, preferably a halogen ion or an alkyl sulfate ion having 1 to 3 carbon atoms. ]. In the present invention, the surfactant used in combination is
Fatty acids or salts thereof, and nonionic surfactants of the general formula (1) and / or (2) are preferred, and compounds of the general formula (2) are particularly preferred. The fungicide composition of the present invention may contain an inorganic salt. However, in order not to suppress the fungicidal and fungicidal effects, the compounding amount is preferably 5% by mass or less in the composition. It is more preferable that the content is not more than 2% by mass, and most preferable that it is not substantially added. In the present invention, it is preferable to contain a hydrotrope for the purpose of improving the storage stability. Hydrotroping agents include toluenesulfonic acid, xylenesulfonic acid, cumenesulfonic acid and their sodium,
Potassium or magnesium salts are good, especially p
-Toluenesulfonic acid and its salts are good. The antifungal composition of the present invention contains the hydrotrope preferably in an amount of 0.001 to 1% by mass, particularly preferably 0.001 to 1% by mass.
It is preferable to contain 0.5% by mass. The pH of the antifungal composition of the present invention at 20 ° C. is preferably 3 to 9, more preferably 4 to 8. pH adjusters include inorganic acids such as hydrochloric acid and sulfuric acid, sodium hydroxide and potassium hydroxide, ammonia and its derivatives, amine salts such as monoethanolamine, diethanolamine and triethanolamine, and alkali agents such as sodium carbonate and potassium carbonate. Are preferably used alone or in combination. Particularly, it is preferable to use an acid selected from hydrochloric acid and sulfuric acid and an alkali agent selected from sodium hydroxide and potassium hydroxide. The antifungal composition of the present invention has a viscosity at 20 ° C. of preferably 15 mPa · s for the purpose of facilitating treatment of an object and improving the antifungal and fungicidal effects.
Hereinafter, the pressure is more preferably 1 to 10 mPa · s. By adjusting the viscosity to such a value, the target object can be uniformly processed, and drying can be further promoted. The antifungal composition of the present invention is preferably used by spraying on an object. As the nebulizer, it is preferable to use a trigger type nebulizer or an aerosol type nebulizer. When a trigger atomizer is used, the atomizer preferably has a stroke of 0.2 g to 2.0 g,
More preferably 0.2 to 1.0 g, particularly preferably 0.2 g to 0.7 g, most preferably 0.25 to 0.5 g.
g What gushes out is good. Particularly preferred as the trigger type spray container used in the present invention is Japanese Utility Model No.
An accumulator trigger as disclosed in JP-A-37554 is particularly good in terms of spray uniformity. When an aerosol sprayer is used, the sprayer preferably sprays 0.5 to 5.0 g per second, more preferably 1.0 to 3.0 g per second. As the propellant for the aerosol, liquefied propane gas, dimethyl ether, nitrogen, carbon dioxide, air and the like can be used. From the viewpoint of injection characteristics, liquefied propane gas is preferred, and from the viewpoint of safety, nitrogen and carbon dioxide are used. Air is preferred. As a spraying characteristic, a trigger type in which the area where the liquid is applied when spraying an object placed vertically on the ground from a distance of 15 cm is preferably 100 to 800 cm ² , more preferably 150 to 600 cm ^2. Nebulizers are preferred. In the present invention, the spray amount of the component (b) is preferably 1 to 10 per 1000 cm ^{2 of} the object.
mg, and more preferably 2 to 5 mg, by spraying the target uniformly and drying it to obtain a high antifungal / fungicidal effect. As a particularly preferable trigger type spray container used in the present invention, a pressure accumulating type trigger disclosed in Japanese Utility Model Laid-Open No. 4-37554 is particularly preferable in terms of spray uniformity. After spraying, it was air-dried. The composition suitable for this method is as described above. EXAMPLES Table 2 was prepared using the component (a) having the composition shown in Table 1.
The following antifungal composition was prepared, and the antifungal effect shown below was evaluated. Table 2 shows the results. <Evaluation of antifungal effect> 50 mm × 50 mm
A test piece was obtained by uniformly inoculating 10 ³ spores of Penicillium aurantiogriseum on a plywood plate. The test piece was placed in a desiccator (48 L) adjusted to 30 ° C./90 RH%, and the test piece was placed at 0.
025 ml of the fungicide composition was sprayed, the desiccator was closed as it was, and the growth of the mold was visually observed after 3 days, 1 week and 2 weeks, and evaluated according to the following criteria. [Table 1] [Table 2] (Note) * 1: The azeotropic temperature is the azeotropic temperature with water at 1013.25 hPa. * 2: Nonionic is an alkyl polyglucoside [the composition of the alkyl group is an alkyl group having 10 carbon atoms / an alkyl group having 12 carbon atoms = 4/6 (mass ratio), and the average degree of glucose condensation is 1.3]. * 3: The pH was adjusted with a 1 / 10N aqueous sulfuric acid solution and a 1 / 10N aqueous sodium hydroxide solution.

──────────────────────────────────────────────────の Continued on the front page (51) Int.Cl. ⁷ Identification symbol FI Theme coat ゛ (Reference) A01N 37/08 A01N 37/08 (72) Inventor Masahiro Suzuki 1334 Minato, Wakayama-shi, Wakayama Pref. (72) Inventor Ban Take 1334 Minato, Wakayama-shi, Wakayama Prefecture Inside Kao Research Institute BB06 BC03 BC18 DD06 DE15 DF04

Claims (1)

Claims: 1. A mixture of acylated glycerol having (a) an acyl group having 6 to 18 carbon atoms, wherein the monoacylated glycerol is 40 to 99.9% by mass in the mixture. 0.005 to 5% by mass of the acylated glycerol mixture,
(B) one or more fragrance components selected from the following fragrances (b-1) and / or natural essential oils (b-2):
5% by mass, (c) forming an azeotrope with water;
A fungicide composition containing 1 to 70% by mass of an organic compound having an azeotropic temperature with water at 25 hPa of less than 100 ° C, and (d) water. (B-1) cinamic aldehyde, chavicol, hexanal, heliotropin, methyl eugenol, p
-Isopropylcyclohexanol, acetophenone,
Isoeugenol, undecanal, ethyl caproate, eugenol, octanol, carvacrol, geraniol, cyclamenaldehyde, cedrol, terpinyl acetate, terpinen, thymol, decanol, phenylacetaldehyde, benzyl acetate,
Perilaldehyde, methyl salicylate, linalyl acetate, linalool, limonene, γ-undecalactone, citral, citronellal, citronellol, nerol, hinokitiol, cinnamic alcohol, l
-Carvone, 1-menthol, terpineol, terpinen-4-ol, camphor, borneol, anisaldehyde, vanillin, ethyl vanillin, α-hexylcinnamic aldehyde, octanal, nonanal,
Decanal, anethole, allyl isothiocyanate (b-2) cumin oil, coriander oil, perilla oil, geranium oil, fennel oil, lavender oil, lemongrass oil, rose oil, laurel oil, origanum oil, orange oil, cassia oil, clove Oil, citronella oil, cinnamon oil, sage oil, thyme oil, dill oil,
Tree moss oil, Hiba oil, Pimento oil, Bay oil, Vetiver oil, Penny royal oil, Peruvian balsam oil, Eucalyptus oil, Lemon oil, Rosemary oil, Tea tree oil, Anise oil, Star anise oil, Palmarosa oil, Peppermint oil, Spearmint oil , Basil oil, hinoki oil, lavandin oil, wasabi oil