CN108865487A - A kind of decontamination lotion and preparation method thereof for hard-surface cleaning - Google Patents
A kind of decontamination lotion and preparation method thereof for hard-surface cleaning Download PDFInfo
- Publication number
- CN108865487A CN108865487A CN201810682302.XA CN201810682302A CN108865487A CN 108865487 A CN108865487 A CN 108865487A CN 201810682302 A CN201810682302 A CN 201810682302A CN 108865487 A CN108865487 A CN 108865487A
- Authority
- CN
- China
- Prior art keywords
- hard
- surface cleaning
- decontamination
- decontamination lotion
- abrasive material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000005202 decontamination Methods 0.000 title claims abstract description 61
- 230000003588 decontaminative effect Effects 0.000 title claims abstract description 61
- 239000006210 lotion Substances 0.000 title claims abstract description 55
- 238000004140 cleaning Methods 0.000 title claims abstract description 41
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 41
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 20
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000003082 abrasive agent Substances 0.000 claims abstract description 20
- 239000008367 deionised water Substances 0.000 claims abstract description 15
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 15
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000004202 carbamide Substances 0.000 claims abstract description 13
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 10
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 9
- 239000002562 thickening agent Substances 0.000 claims abstract description 9
- 239000003755 preservative agent Substances 0.000 claims abstract description 8
- 230000002335 preservative effect Effects 0.000 claims abstract description 8
- 229910021532 Calcite Inorganic materials 0.000 claims description 33
- 239000000843 powder Substances 0.000 claims description 32
- 239000004115 Sodium Silicate Substances 0.000 claims description 16
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 16
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 16
- 235000019795 sodium metasilicate Nutrition 0.000 claims description 16
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 16
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 16
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 13
- 238000003756 stirring Methods 0.000 claims description 13
- AEQDJSLRWYMAQI-UHFFFAOYSA-N 2,3,9,10-tetramethoxy-6,8,13,13a-tetrahydro-5H-isoquinolino[2,1-b]isoquinoline Chemical compound C1CN2CC(C(=C(OC)C=C3)OC)=C3CC2C2=C1C=C(OC)C(OC)=C2 AEQDJSLRWYMAQI-UHFFFAOYSA-N 0.000 claims description 12
- 239000000176 sodium gluconate Substances 0.000 claims description 12
- 235000012207 sodium gluconate Nutrition 0.000 claims description 12
- 229940005574 sodium gluconate Drugs 0.000 claims description 12
- 150000002191 fatty alcohols Chemical class 0.000 claims description 11
- 229920001661 Chitosan Polymers 0.000 claims description 10
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 10
- 239000003109 Disodium ethylene diamine tetraacetate Substances 0.000 claims description 8
- 235000019301 disodium ethylene diamine tetraacetate Nutrition 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims 2
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 claims 2
- 239000004698 Polyethylene Substances 0.000 claims 1
- 125000000129 anionic group Chemical group 0.000 claims 1
- 229940124274 edetate disodium Drugs 0.000 claims 1
- 229940031098 ethanolamine Drugs 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 35
- 239000003599 detergent Substances 0.000 abstract description 12
- 239000011521 glass Substances 0.000 abstract description 9
- 229910001220 stainless steel Inorganic materials 0.000 abstract description 9
- 239000010935 stainless steel Substances 0.000 abstract description 9
- 239000004094 surface-active agent Substances 0.000 abstract description 6
- 239000000919 ceramic Substances 0.000 abstract description 5
- 239000004579 marble Substances 0.000 abstract description 4
- 229920000965 Duroplast Polymers 0.000 abstract description 3
- 230000009471 action Effects 0.000 abstract description 3
- 238000009390 chemical decontamination Methods 0.000 abstract description 3
- 230000000052 comparative effect Effects 0.000 description 52
- 230000003746 surface roughness Effects 0.000 description 14
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 12
- 230000007797 corrosion Effects 0.000 description 10
- 238000005260 corrosion Methods 0.000 description 10
- 235000019441 ethanol Nutrition 0.000 description 10
- -1 sodium alkyl benzene Chemical class 0.000 description 10
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 9
- 238000000034 method Methods 0.000 description 9
- 239000011734 sodium Substances 0.000 description 9
- 229910052708 sodium Inorganic materials 0.000 description 9
- 229910052751 metal Inorganic materials 0.000 description 8
- 239000000428 dust Substances 0.000 description 7
- 239000002184 metal Substances 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 6
- 229910000019 calcium carbonate Inorganic materials 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 239000002253 acid Substances 0.000 description 5
- 235000011187 glycerol Nutrition 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- QZPSOSOOLFHYRR-UHFFFAOYSA-N 3-hydroxypropyl prop-2-enoate Chemical compound OCCCOC(=O)C=C QZPSOSOOLFHYRR-UHFFFAOYSA-N 0.000 description 4
- 241000276489 Merlangius merlangus Species 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- 238000013475 authorization Methods 0.000 description 4
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 4
- 239000004519 grease Substances 0.000 description 4
- 229910001385 heavy metal Inorganic materials 0.000 description 4
- 150000002500 ions Chemical class 0.000 description 4
- 239000003350 kerosene Substances 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 3
- 241001074085 Scophthalmus aquosus Species 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 239000005864 Sulphur Substances 0.000 description 3
- 238000005299 abrasion Methods 0.000 description 3
- 229940077388 benzenesulfonate Drugs 0.000 description 3
- 239000008233 hard water Substances 0.000 description 3
- 239000003112 inhibitor Substances 0.000 description 3
- 230000005764 inhibitory process Effects 0.000 description 3
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 3
- MGIYRDNGCNKGJU-UHFFFAOYSA-N isothiazolinone Chemical compound O=C1C=CSN1 MGIYRDNGCNKGJU-UHFFFAOYSA-N 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 238000005498 polishing Methods 0.000 description 3
- 229910052573 porcelain Inorganic materials 0.000 description 3
- 230000001376 precipitating effect Effects 0.000 description 3
- 230000002829 reductive effect Effects 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- 210000002700 urine Anatomy 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- MBBZMMPHUWSWHV-BDVNFPICSA-N N-methylglucamine Chemical compound CNC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO MBBZMMPHUWSWHV-BDVNFPICSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000001354 calcination Methods 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229910001424 calcium ion Inorganic materials 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 239000002738 chelating agent Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000012459 cleaning agent Substances 0.000 description 2
- 239000000356 contaminant Substances 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 238000004945 emulsification Methods 0.000 description 2
- BEGBSFPALGFMJI-UHFFFAOYSA-N ethene;sodium Chemical group [Na].C=C BEGBSFPALGFMJI-UHFFFAOYSA-N 0.000 description 2
- 229940071106 ethylenediaminetetraacetate Drugs 0.000 description 2
- 230000004907 flux Effects 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- 210000002374 sebum Anatomy 0.000 description 2
- 239000000779 smoke Substances 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- 239000008234 soft water Substances 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 238000010186 staining Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000000037 vitreous enamel Substances 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- AMULJSVDIHMAOX-UHFFFAOYSA-N 3-hydroxypropyl prop-2-enoate;prop-2-enoic acid Chemical compound OC(=O)C=C.OCCCOC(=O)C=C AMULJSVDIHMAOX-UHFFFAOYSA-N 0.000 description 1
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- 241000222122 Candida albicans Species 0.000 description 1
- 229920002101 Chitin Polymers 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 239000006173 Good's buffer Substances 0.000 description 1
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 241000191967 Staphylococcus aureus Species 0.000 description 1
- 241000270666 Testudines Species 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- VQLYBLABXAHUDN-UHFFFAOYSA-N bis(4-fluorophenyl)-methyl-(1,2,4-triazol-1-ylmethyl)silane;methyl n-(1h-benzimidazol-2-yl)carbamate Chemical compound C1=CC=C2NC(NC(=O)OC)=NC2=C1.C=1C=C(F)C=CC=1[Si](C=1C=CC(F)=CC=1)(C)CN1C=NC=N1 VQLYBLABXAHUDN-UHFFFAOYSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- FYHXNYLLNIKZMR-UHFFFAOYSA-N calcium;carbonic acid Chemical compound [Ca].OC(O)=O FYHXNYLLNIKZMR-UHFFFAOYSA-N 0.000 description 1
- 229940095731 candida albicans Drugs 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000013522 chelant Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 238000010668 complexation reaction Methods 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 239000006184 cosolvent Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 238000003487 electrochemical reaction Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000003349 gelling agent Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 229910001425 magnesium ion Inorganic materials 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 235000019592 roughness Nutrition 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- UPMFZISCCZSDND-JJKGCWMISA-M sodium gluconate Chemical compound [Na+].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O UPMFZISCCZSDND-JJKGCWMISA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/08—Silicates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/1233—Carbonates, e.g. calcite or dolomite
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/32—Amides; Substituted amides
- C11D3/323—Amides; Substituted amides urea or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
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Abstract
The decontamination lotion and preparation method thereof that the invention discloses a kind of for hard-surface cleaning, belong to detergent technical field, its key points of the technical solution are that a kind of decontamination lotion for hard-surface cleaning includes water softener 0.1-0.5wt%, preservative 0.1-0.5wt%, urea 0.9-1.5wt%, anionic surfactant 4-10wt%, nonionic surfactant 4-10wt%, ether 4-10wt%, Organic Alcohol 0.9-1.9wt%, thickener 0.5-1.9wt%, abrasive material 20-39wt%, essence 0.1-0.3wt% and deionized water 24.4-65.4wt%.Decontamination lotion of the invention has chemical decontamination function and physics descaling function concurrently, there is excellent cleaning de-sludging effect to the stain on the hard surfaces such as ceramics, stainless steel, marble, duroplasts, glass, in addition to general surfactant bring dirt-removing power, it also has the significant rubbing action of abrasive material bring concurrently, there is excellent cleaning effect to the dirt on implements hard surface.
Description
Technical field
It is the present invention relates to detergent technical field, in particular to a kind of for the decontamination lotion of hard-surface cleaning and its preparation
Method.
Background technique
Detergent is the product of particular formulation for cleaning, main component usually by surfactant, builder and
The composition such as additive；There are many type of detergent, can be divided into powdery, bulk, paste, pulpous state and liquid etc. according to the shape of product
Variform.
The prior art can refer to the Chinese patent that Authorization Notice No. is CN103555450B, and it discloses a kind of antibacterial decontaminations
Liquid detergent and preparation method thereof, raw material include sodium alkyl benzene sulfonate 5-10wt%, lauryl sodium sulfate 2-5wt%,
Fatty alcohol polyoxyethylene ether 5-10wt%, methyl glucamine 0.5-1wt%, glycosyl amide quaternary ammonium salt 1-2wt%, essence
0.05-0.2wt%, deionized water surplus.But sodium alkyl benzene sulfonate, lauryl sodium sulfate, fatty alcohol polyoxyethylene ether with
And glycosyl amide quaternary ammonium salt is surfactant, can play the role of to the spot of body surface emulsification it is clean, but by
It is limited in the cleaning capacity of surfactant, there is serious spot for surface or has the cleaning capacity of the object of rust staining bad,
It is unable to reach good clean effect.
Existing to can refer to the Chinese patent that Authorization Notice No. is CN10049433C, it discloses one kind for ware
Ware, enamelware, glassware, plastic products and aluminum products surface and oil contaminant and dirt be purged and the high-effective cleansing that uses
Powder.It is using flux calcination diatomite as major ingredient, with sodium n-alkylbenzenesulfonate, sodium carbonate or soap powder, dichlord isocyanurice acid
Sodium and essence are that auxiliary material mixed preparing forms.Although the cleanser of the invention can be to particulate fouling, protein dirt, oily dirt
And dust has stronger dirt-removing power, but its state of matter is solid-state, is needed when in use by itself and water with suitable
Ratio mixing after, could need to adjust its concentration when this requires using every time to relatively good clean effect is played
Match, it is inconvenient.
The existing patent application document that can refer to application publication number CN105925394A, it discloses a kind of hard-surface cleanings
Decontamination lotion is prepared by the raw material of following parts by weight：Anionic surfactant dodecyl alcohol polyoxyethylene
30-40 parts of ether sodium sulfate；25-35 parts of nonionic surfactant fatty alcohol polyoxyethylene ether；Natural whiting mild abrasive 10-
20 parts；2-4 parts of sodium ethylene diamine tetracetate；35-45 parts of water；It further include that auxiliary agent hydroxypropyl acrylate and kerosene are 6-8 parts total, acrylic acid
Hydroxypropyl acrylate and kerosene weight ratio are 5-7:1.Although calcium carbonate, which can be used as a kind of friction base-material, can play serious spot
To clean effect, but since the particle of the calcium carbonate is big, specific gravity is high, hardness is hard, transportation cost is high, it is easy scratch article table
Face influences appearance and finish；Furthermore hydroxypropyl acrylate is toxic, when skin or eye contact, can cause prominent disease, manufacture
When with certain risk.
Therefore how to prepare it is a kind of it is easy to use, clean effect is good, is suitable for hard-surface cleaning and to article surface
Damaging small decontamination lotion is a problem to be solved.
Summary of the invention
One of the objects of the present invention is to provide a kind of decontamination lotions for hard-surface cleaning, have chemical decontamination function concurrently
Can and physics descaling function, have to the stain on the hard surfaces such as ceramics, stainless steel, marble, duroplasts, glass excellent clear
Clean de-sludging effect also has the significant rubbing action of abrasive material bring concurrently in addition to general surfactant bring dirt-removing power,
There is excellent cleaning effect to the dirt on implements hard surface.
Above-mentioned technical purpose of the invention technical scheme is that：
A kind of decontamination lotion for hard-surface cleaning, including water softener 0.1-0.5wt%, preservative 0.1-0.5wt%, urea
It is 0.9-1.5wt%, anionic surfactant 4-10wt%, nonionic surfactant 4-10wt%, ether 4-10wt%, organic
Alcohol 0.9-1.9wt%, thickener 0.5-1.9wt%, abrasive material 20-39wt%, essence 0.1-0.3wt% and deionized water
24.4-65.4wt%.
By using above-mentioned technical proposal, water softener has very strong sequestering power to heavy metal ion, can be these metals
Ion is closed, in order to avoid heavy metal ion has an adverse effect to detergent, is improved pre-treatment quality, is emulsified dirt；Urea
It is colourless or white needles or rodlike crystalline solid, is dissolved in water, alcohol, the Organic Alcohol in component can increase the solution rate of urea,
Urea inhibits staphylococcus aureus, Candida albicans, and almost without side effect, for metal equipment, advantage
It is not corrode metal, and have enhanced shine to steel, stainless steel chemical polishing, corrosion inhibiter, inhibition is used as in pickling of metal
Agent can be prevented from or slow down the chemical substance of material corrosion, can be referred to as corrosion inhibitor, be used for neutral medium (boiler
With water, recirculated cooling water), acid medium and gas medium；Anionic surfactant can be played with nonionic surfactant
The effect of chemical decontamination；Thickener can improve the concentration of decontamination lotion, when using decontamination lotion, can reduce the flowing speed of fluid
Degree extends decontamination lotion in the residence time on cleaned object surface, saves dosage, enhance clean effect；Abrasive material bring is significant
Rubbing action, on implements hard surface dirt or rust staining there is the cleaning function that does not have of Common detergents；
The present invention is further arranged to：The abrasive material is calcite in powder, and the granularity of the calcite in powder is 200 mesh.
By using above-mentioned technical proposal, calcite is the abbreviation of powdered whiting, a kind of calcium carbonate mineral, clear, colorless
Or white, sometimes containing variegated, most common in natural whiting is exactly it；The main component of calcite is CaCO3, theorize
It is 56.03%, CO that group, which becomes CaO,2It is 43.97%, often contains Mn and Fe, contains Sr sometimes；Calcite in powder is generally white, milky white
Color is colourless, has glassy lustre, 898.6 DEG C of decomposition temperature, compact structure is insoluble in water, is dissolved in acid, and impurity is few, and granularity is equal
Even, process industrial art performance is good；The graininess of calcite in powder is good, and hardness is moderate, it is necessary to frictional property, be conducive to remove hard surface
Dirt on implements, and be that the calcite of 200 mesh can be reduced so that it will not scratch implements surface to implements because selecting granularity
Abrasion.
The present invention is further arranged to：The water softener includes disodium ethylene diamine tetraacetate, sodium metasilicate and gluconic acid
Sodium, the weight ratio of the disodium ethylene diamine tetraacetate, sodium metasilicate and sodium gluconate are 3:1:1.
By using above-mentioned technical proposal, the ability of disodium ethylene diamine tetraacetate (EDTA) huge legendary turtle and calcium ion is current soft water
Strongest one kind in agent, but the disadvantage is that alkalinity cannot be provided for detergent, it is saponified fatty soil；And sodium metasilicate can provide
Alkalinity, makes up the defect of EDTA, and has good buffer function, and the pH value of cleaning solution can be maintained to continue 9.5, because of dirt
Nearly all be it is acid, pH value reduction can be such that washability declines, therefore can be improved clean effect；Sodium metasilicate can also make to wash
Calcium and magnesium ion in liquid generates insoluble silicate and precipitating softens water, and the precipitating generated is easy to be floated with water to remove, and can also make
The dirt of removing is suspended in cleaning solution, also can on vitreous enamel, monomolecular film is formed on porcelain, the film have antiredeposition
Effect；Sodium metasilicate belongs to anodic corrosion inhibitor, can achieve the purpose that inhibition by the anodic process suppressed corrosion reaction,
Cooperating with urea can be to extension corrosion of metal；Sodium metasilicate also has good wetting and emulsibility；It can make acid dirt
Saponification and the emulsification to grease, effectively improve detersive efficiency.
Sodium gluconate can make highly effective chelating agent, steel surface cleaning agent and glass cleaner, and sodium gluconate is nontoxic,
The sodium gluconate being present in water and its chelate formed with heavy metal ion, can be rapid, complete by common biochemical treatment
It degrades entirely, the heavy metal ion released in degradation process can be removed through precipitating, or be adsorbed in wastewater treatment process and formed
Mud on and remove, meet environmental requirement.
The present invention is further arranged to：The anionic surfactant includes neopelex；It is described it is non-from
Sub- surfactant includes fatty alcohol polyoxyethylene ether.
By using above-mentioned technical proposal, neopelex has particulate fouling, albumen dirt and oily dirt
Significant clean effect, detergency enhance with the raising of wash temperature, living higher than non-ionic surface to the effect of albumen dirt
Property agent, but the resistance to hard water of neopelex is poor, and detergency ability can be reduced with the hardness of water, therefore the soft water added
Agent can make up this defect of neopelex；Although the degreasing power of neopelex is stronger, hand washing
When have certain irritation to skin, therefore be preferably often used in compounding with fatty alcohol polyoxyethylene ether with neopelex.
The present invention is further arranged to：The ether includes glycerin polyoxyethylene ether.
By using above-mentioned technical proposal, glycerin polyoxyethylene ether has excellent foam stabilizing, wetting, infiltration, lubrication, solubilising
And moisture-retaining capacity, solvent, cosolvent and viscosity modifier can be done.
The present invention is further arranged to：The Organic Alcohol includes ethyl alcohol.
By using above-mentioned technical proposal, ethyl alcohol can be used as the organic solvent of urea, and it is living with non-ionic surface to improve it
The using effect of property agent and anionic surfactant.
The present invention is further arranged to：The thickener includes triethanolamine and chitosan, the triethanolamine and
The weight ratio of chitosan is 2:1.
By using above-mentioned technical proposal, triethanolamine can improve oily dirt, the especially removal of nonpolarity sebum,
Meanwhile detergency ability can be improved by improving alkalinity, and have its fabulous compatibility；The main component of chitosan has carbonic acid
Calcium, protein and chitin, industry in be used as adhesive, thickener, stabilizer, gelling agent；Triethanolamine is common with chitosan
The viscosity that decontamination lotion can be improved is conducive to be wrapped in abrasive material in decontamination lotion, improves the clean effect of decontamination lotion.
The second object of the present invention is to improve a kind of preparation method of decontamination lotion for hard-surface cleaning.
Above-mentioned technical purpose of the invention technical scheme is that：
A kind of preparation method of the decontamination lotion for hard-surface cleaning, includes the following steps：
(1) it is pre-mixed：Deionized water is divided into two parts, then first part of deionized water is added in batching kettle and is heated to 85-
95 DEG C, anionic surfactant, nonionic surfactant, water softener and abrasive material is then added, in 500-550r/min
Revolving speed under stir 10-20min；
(2) it prepares：Preservative is sequentially added into premix, urea, ether, Organic Alcohol, thickener, essence and second part are gone
Ionized water stirs 50-60min under the revolving speed of 200-300r/min, and abrasive material is then added under the revolving speed of 300-400r/min
60-90min is stirred to get the decontamination lotion arrived for hard-surface cleaning.
Abrasive material is set to be scattered in decontamination lotion the raw material batch mixed in decontamination lotion by using above-mentioned technical proposal
In, decontamination lotion can be shaken in advance when in use, be conducive to the evenly dispersed of abrasive material, to improve clean effect.
In conclusion the present invention has the advantages that compared with the prior art：
1. the graininess of calcite in powder is good, hardness is moderate, it is necessary to frictional property, be conducive to remove hard surface implements on dirt
Dirt, and be that the calcite of 200 mesh can be reduced the abrasion to implements so that it will not scratch implements surface because selecting granularity.
2. disodium ethylene diamine tetraacetate energy complexation of metal ions, sodium gluconate is nontoxic, can make highly effective chelating agent, steel table
Face cleaning agent and glass cleaner；Sodium metasilicate can be improved the alkalinity of detergent, improve clean effect, and sodium metasilicate can also make to take off
The dirt removed is suspended in cleaning solution, also can on vitreous enamel, monomolecular film is formed on porcelain, the film with antiredeposition make
With；Sodium metasilicate belongs to anodic corrosion inhibitor, can achieve the purpose that inhibition by the anodic process suppressed corrosion reaction, with
Urea mutual cooperation can extend hard water to corrosion of metal；
3. triethanolamine, oily dirt can be improved, the removal of especially nonpolar sebum, and by can be improved alkalinity to
Improve detergency ability；Constituent of chitosan is environmentally friendly, and can improve the viscosity of decontamination lotion jointly with triethanolamine, is conducive to grind
Material is wrapped in decontamination lotion, improves the clean effect of decontamination lotion.
Detailed description of the invention
Fig. 1 is the decontamination lotion of embodiment 1 and comparative example 6-18 preparation to wiping time of the dirt in kitchen tile
Line chart；
Fig. 2 is the table of the kitchen tile after the decontamination lotion prepared with embodiment 1 and comparative example 6-18 wipes kitchen tile
The line chart of surface roughness.
Specific embodiment
Invention is further described in detail below.
One, embodiment 1-3
Embodiment 1：A kind of decontamination lotion for hard-surface cleaning is prepared with the following method：
(1) it is pre-mixed：22.1kg deionized water is added in batching kettle and is heated to 90 DEG C, 7kg detergent alkylate sulphur is then added
Sour sodium, 7kg fatty alcohol polyoxyethylene ether, 0.18kg disodium ethylene diamine tetraacetate, 0.06kg sodium metasilicate, 0.06kg sodium gluconate
And 30kg granularity is the calcite in powder of 200 mesh, stirs 15min under the revolving speed of 525r/min；
(2) it prepares：0.3kg isothiazolinone preservative, 1.2kg, the urine that nitrogen content is 46% are sequentially added into premix
Element, 7kg glycerin polyoxyethylene ether, 1.4kg ethyl alcohol, 0.93kg triethanolamine, 0.47kg chitosan, 0.2kg essence and
22.1kg deionized water stirs 55min under the revolving speed of 250r/min, and abrasive material is then added and stirs under the revolving speed of 350r/min
75min is mixed to get the decontamination lotion arrived for hard-surface cleaning.
Embodiment 2：A kind of decontamination lotion for hard-surface cleaning is prepared with the following method：
(1) it is pre-mixed：22.5kg deionized water is added in batching kettle and is heated to 85 DEG C, 4kg detergent alkylate sulphur is then added
Sour sodium, 4kg fatty alcohol polyoxyethylene ether, 0.06kg disodium ethylene diamine tetraacetate, 0.02kg sodium metasilicate, 0.02kg sodium gluconate
And 20kg granularity is the calcite in powder of 200 mesh, stirs 20min under the revolving speed of 500r/min；
(2) it prepares：0.1kg isothiazolinone preservative, 0.9kg, the urine that nitrogen content is 46% are sequentially added into premix
Element, 4kg glycerin polyoxyethylene ether, 0.9kg ethyl alcohol, 1.27kg triethanolamine, 0.63kg chitosan, 0.1kg essence and
22.5kg deionized water stirs 60min under the revolving speed of 200r/min, and abrasive material is then added and stirs under the revolving speed of 300r/min
60min is mixed to get the decontamination lotion arrived for hard-surface cleaning.
Embodiment 3：A kind of decontamination lotion for hard-surface cleaning is prepared with the following method：
(1) it is pre-mixed：22.4kg deionized water is added in batching kettle and is heated to 85 DEG C, 10kg detergent alkylate sulphur is then added
Sour sodium, 10kg fatty alcohol polyoxyethylene ether, 0.3kg disodium ethylene diamine tetraacetate, 0.1kg sodium metasilicate, 0.06kg sodium gluconate
And 39kg granularity is the calcite in powder of 200 mesh, stirs 10min under the revolving speed of 550r/min；
(2) it prepares：0.5kg isothiazolinone preservative, 1.5kg, the urine that nitrogen content is 46% are sequentially added into premix
Element, 10kg glycerin polyoxyethylene ether, 1.9kg ethyl alcohol, 0.33kg triethanolamine, 0.17kg chitosan, 0.3kg essence and
22.4kg deionized water stirs 50min under the revolving speed of 300r/min, and abrasive material is then added and stirs under the revolving speed of 400r/min
60min is mixed to get the decontamination lotion arrived for hard-surface cleaning.
Two, comparative example 1-18
Comparative example 1：Use Authorization Notice No. for the Chinese patent of CN103555450B, it discloses a kind of antibacterial decontaminating liquids to wash
Agent and preparation method thereof is washed, raw material includes sodium alkyl benzene sulfonate 5-10wt%, lauryl sodium sulfate 2-5wt%, fatty alcohol
Polyoxyethylene ether 5-10wt%, methyl glucamine 0.5-1wt%, glycosyl amide quaternary ammonium salt 1-2wt%, essence 0.05-
0.2wt%, deionized water surplus.
Comparative example 2：Use reference Authorization Notice No. for the Chinese patent of CN10049433C, it discloses one kind for pair
Pottery, enamelware, glassware, plastic products and aluminum products surface and oil contaminant and dirt be purged and the height that uses
Imitate cleanser.It is using flux calcination diatomite as major ingredient, it is different with sodium n-alkylbenzenesulfonate, sodium carbonate or soap powder, dichloro
NaDCC and essence are that auxiliary material mixed preparing forms.
Comparative example 3：Using the patent application document of application reference publication No. CN105925394A, it discloses a kind of hard tables
The Clean- decontamination lotion in face, is prepared by the raw material of following parts by weight：Anionic surfactant dodecyl alcohol is poly-
30-40 parts of ethylene oxide ether sodium sulfate；25-35 parts of nonionic surfactant fatty alcohol polyoxyethylene ether；Natural whiting is soft
10-20 parts of abrasive material；2-4 parts of sodium ethylene diamine tetracetate；35-45 parts of water；It further include auxiliary agent hydroxypropyl acrylate and the total 6-8 of kerosene
Part, hydroxypropyl acrylate and kerosene weight ratio are 5-7:1.
Comparative example 4：Comparative example 4 is difference from example 1 is that be not added with urea and sodium metasilicate.
Comparative example 5：Comparative example 5 is difference from example 1 is that be not added with sodium gluconate.
Comparative example 6：Comparative example 6 is difference from example 1 is that the granularity of calcite in powder is 160 mesh.
Comparative example 7：Comparative example 7 is difference from example 1 is that the granularity of calcite in powder is 165 mesh.
Comparative example 8：Comparative example 8 is difference from example 1 is that the granularity of calcite in powder is 170 mesh.
Comparative example 9：Comparative example 9 is difference from example 1 is that the granularity of calcite in powder is 175 mesh.
Comparative example 10：Comparative example 10 is difference from example 1 is that the granularity of calcite in powder is 180 mesh.
Comparative example 11：Comparative example 11 is difference from example 1 is that the granularity of calcite in powder is 185 mesh.
Comparative example 12：Comparative example 12 is difference from example 1 is that the granularity of calcite in powder is 190 mesh.
Comparative example 13：Comparative example 13 is difference from example 1 is that the granularity of calcite in powder is 195 mesh.
Comparative example 14：Comparative example 14 is difference from example 1 is that the granularity of calcite in powder is 205 mesh.
Comparative example 15：Comparative example 15 is difference from example 1 is that the granularity of calcite in powder is 210 mesh.
Comparative example 16：Comparative example 16 is difference from example 1 is that the granularity of calcite in powder is 215 mesh.
Comparative example 17：Comparative example 17 is difference from example 1 is that the granularity of calcite in powder is 220 mesh.
Comparative example 18：Comparative example 18 is difference from example 1 is that the granularity of calcite in powder is 225 mesh.
Three, the performance of embodiment 1-3 and comparative example 1-18 are tested.
1/4 water that its cleanser weight is added in the cleanser prepared to comparative example 2 is uniformly mixed, and decontamination liquid is made,
The decontamination lotion for taking 100ml embodiment 1-3, comparative example 1-18 to prepare respectively is tested.
1, clean effect is tested:Select the hard surface article for being attached with uniform dirt as sample, respectively to embodiment 1-3
And the clean effect of the decontamination lotion of comparative example 1-6 is tested, and decontamination lotion is dipped with cotton yarn, with identical frequency and power
Degree is wiped repeatedly sample, and the time removed using dirt as experimental result, shows the result in table 1.
Wherein hard surface article selects following region respectively：
Sample is 1.：Kitchen tile；Since oil smoke is bigger, the dirt in kitchen tile is mainly grease and dust in kitchen.
Sample is 2.：On the inside of the windowpane of kitchen：Kitchen glass, for a long time can be in glass because being in the bigger environment of oil smoke
Upper accumulation grease soils and dust.
Sample is 3.：On the outside of the windowpane of kitchen：Dust that can be outdoor on the outside of windowpane is excessive and is attached on glass, with ash
The long-time of dirt is accumulated, and will form more thick and heavy dirt.
Sample is 4.：Kitchen marble hearth：Marmorean main component is calcium carbonate, has more oil in kitchen
Rouge and dust are attached to its surface and are difficult to clear up.
Sample is 5.：Toilet ceramic bowl：The ceramic bowl of toilet is because of Long Term Contact water, and the hardness of water is different, with hard water
Heating can generate scale in toilet ceramic bowl, and the main component of scale includes calcium carbonate, magnesium carbonate, calcium sulfate, magnesium sulfate, chlorine
Change calcium, magnesium chloride etc..
Sample is 6.：Toilet stainless steel shower：The surface layer of stainless steel has protective film, will not typically get rusty
, but stainless steel surface adhere to other metallic elements dust or disparate metals particle attachment when, in wet air
In, attachment can form a micro cell with the condensed water on stainless steel, cause electrochemical reaction, protective film receives destruction, draws
Play corrosion.
The detergency ability of the decontamination lotion of table 1 embodiment 1-3 and comparative example 1-5 preparation tests table
As can be seen from the above data, the present embodiment 1-3 is having more excellent clean effect to the sample in varying environment；
Wherein the clean effect of comparative example 1 is poor, and the clean effect of the sample mixed for grease and dust is bad；Comparative example 2 with it is right
The decontamination level of ratio 3 remains basically stable, but comparative example 2 is needed in use plus water is formulated as solution, inconvenient to use, and
It prepares for the user, is difficult to control preparation and is readily easy, to will affect using effect；It is not added in comparative example 5
Urea and sodium metasilicate reduce decontamination lotion effect of dirt on cleaning stainless steel；Comparative example 6 is not added with sodium gluconate,
Making the effect of its dirt on cleaning glass reduces.
2, surface roughness is tested:Surface roughness refers to the injustice of the smaller spacing that finished surface has and small peak valley
Degree, surface roughness is smaller, then surface is more smooth, and different surface roughnesses is shown in table 2.By the sample after decontamination processing with clearly
After water is rinsed well, with the surface roughness of surface roughness tester detection sample wiped area, table 3 is shown the result in.
The different surface roughness of table 2
The polishing machine of the decontamination lotion of table 3 embodiment 1-3 and comparative example 1-5 preparation tests table
As can be seen from Table 3, the surface roughness by the sample of embodiment 1-3, comparative example 1 and comparative example 4-5 is equal<0.4,
Surface roughness is low, then smoothness is high, illustrates that decontamination lotion prepared by the present invention is small to the scuffing of specimen surface；And comparative example 2-
3 clean effect is good, but the surface roughness of its treated sample is big, big to the scuffing of specimen surface.
3, to hard surface implements after the clean effect of decontamination lotion its decontamination prepared embodiment 1 and comparative example 6-18
Surface roughness tested using above-mentioned test method, and test result is shown in table 4.
The detergency ability and polishing machine of 4 embodiment 1 of table and the decontamination lotion of comparative example 6-18 preparation test table
Data shown in table 4 are converted into line chart, as depicted in figs. 1 and 2, as can be seen from the above data, with calcite in powder
The wiping time of the increase of granularity, decontamination is gradually shortened, but after the granularity of calcite in powder is more than 200 mesh, when wiping
Between amplitude of variation become smaller, illustrate the granularity and non-exhibiting linear increase of clean effect and calcite in powder；And with calcite powder
The increase of degree is gradually increased the degree of roughness on cleaned object surface, illustrates calcite in powder granularity to the mill on cleaned object surface
Damage has larger impact；Comprehensively consider in conjunction with the wiping time with surface roughness, when the granularity of calcite in powder is 200 mesh, decontamination
Lotion is preferable to the clean effect of hard surface implements, and also can abrasion to cleaned object surface it is smaller.
In conclusion the clean effect of decontamination lotion prepared by the present invention is good, to stain to exchange views ability good, to pottery
Stain on the hard surfaces such as porcelain, stainless steel, marble, duroplasts, glass has excellent cleaning effect, and due to its abrasive material
Partial size it is smaller, in the article cleaning to hard surface, the surface roughness of article is low, small to the scuffing of article surface, this
The finished product of outer decontamination lotion is liquid, can directly act on cleaned object when in use, do not need manually to its concentration into
Row allotment, simplifies application method, facilitates operation.
The above is only a preferred embodiment of the present invention, protection scope of the present invention is not limited merely to above-mentioned implementation
Example, all technical solutions belonged under thinking of the present invention all belong to the scope of protection of the present invention.It should be pointed out that for the art
Those of ordinary skill for, several improvements and modifications without departing from the principles of the present invention, these improvements and modifications
It should be regarded as protection scope of the present invention.
Claims (8)
1. a kind of decontamination lotion for hard-surface cleaning, it is characterised in that：Including water softener 0.1-0.5wt%, preservative
0.1-0.5wt%, urea 0.9-1.5wt%, anionic surfactant 4-10wt%, nonionic surfactant 4-
10wt%, ether 4-10wt%, Organic Alcohol 0.9-1.9wt%, thickener 0.5-1.9wt%, abrasive material 20-39wt%, essence 0.1-
0.3wt% and deionized water 24.4-65.4wt%.
2. the decontamination lotion according to claim 1 for hard-surface cleaning, it is characterised in that：The abrasive material is calcite
Powder, the granularity of the calcite in powder are 200 mesh.
3. the decontamination lotion according to claim 1 for hard-surface cleaning, it is characterised in that：The water softener includes second
Edetate disodium, sodium metasilicate and sodium gluconate, the disodium ethylene diamine tetraacetate, sodium metasilicate and sodium gluconate
Weight ratio be 3:1:1.
4. the decontamination lotion according to claim 1 for hard-surface cleaning, it is characterised in that：The anionic surface is living
Property agent includes neopelex；The nonionic surfactant includes fatty alcohol polyoxyethylene ether.
5. the decontamination lotion according to claim 1 for hard-surface cleaning, it is characterised in that：The ether includes that glycerol is poly-
Ethylene oxide ether.
6. the decontamination lotion according to claim 1 for hard-surface cleaning, it is characterised in that：The Organic Alcohol includes second
Alcohol.
7. the decontamination lotion according to claim 1 for hard-surface cleaning, it is characterised in that：The thickener includes three
The weight ratio of ethanol amine and chitosan, the triethanolamine and chitosan is 2:1.
8. a kind of preparation method of the decontamination lotion for hard-surface cleaning, it is characterised in that：Include the following steps：
(1) it is pre-mixed：Deionized water is divided into two parts, then first part of deionized water is added in batching kettle and is heated to 85-
95 DEG C, anionic surfactant, nonionic surfactant, water softener and abrasive material is then added, in 500-550r/min
Revolving speed under stir 10-20min；
(2) it prepares：Preservative is sequentially added into premix, urea, ether, Organic Alcohol, thickener, essence and second part are gone
Ionized water stirs 50-60min under the revolving speed of 200-300r/min, and abrasive material is then added under the revolving speed of 300-400r/min
60-90min is stirred to get the decontamination lotion arrived for hard-surface cleaning.
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| CN109487282A (en) * | 2018-12-11 | 2019-03-19 | 西安庄信新材料科技有限公司 | A kind of titanium building materials high-duty detergent and its preparation process |
| CN109777654A (en) * | 2019-01-28 | 2019-05-21 | 广州世腾建材有限公司 | A kind of stone surface detergent |
| CN111718802A (en) * | 2020-06-22 | 2020-09-29 | 徐州东鑫铸造有限公司 | Mechanical part oil stain cleaning agent and preparation method thereof |
| CN112376059A (en) * | 2020-10-27 | 2021-02-19 | 深圳市贝加电子材料有限公司 | Copper surface degreasing agent and composition, preparation method and application thereof |
| CN112961738A (en) * | 2021-02-05 | 2021-06-15 | 上海佐航新材料科技有限公司 | Novel alkaline hard floor cleaning agent and preparation method thereof |
| CN113105952A (en) * | 2021-03-11 | 2021-07-13 | 江西车仆实业有限公司 | Automobile glass cleaning agent and preparation method and application thereof |
| CN113502192A (en) * | 2021-06-25 | 2021-10-15 | 深圳万洁物业科技服务有限公司 | Special environment-friendly cleaning agent for silicon PU (polyurethane) field and preparation method and application thereof |
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| CN112376059B (en) * | 2020-10-27 | 2023-04-25 | 深圳市贝加电子材料有限公司 | Copper surface degreasing agent, composition, preparation method and application thereof |
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| CN113105952A (en) * | 2021-03-11 | 2021-07-13 | 江西车仆实业有限公司 | Automobile glass cleaning agent and preparation method and application thereof |
| CN113502192A (en) * | 2021-06-25 | 2021-10-15 | 深圳万洁物业科技服务有限公司 | Special environment-friendly cleaning agent for silicon PU (polyurethane) field and preparation method and application thereof |
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