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CH692411A5 - Well tolerated aqueous insect repellent gel for skin protection, containing carbomer, polyoxyethylene hydrogenated castor oil, denatured ethanol and citronella and geranium essential oils - Google Patents

Well tolerated aqueous insect repellent gel for skin protection, containing carbomer, polyoxyethylene hydrogenated castor oil, denatured ethanol and citronella and geranium essential oils Download PDF

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Publication number
CH692411A5
CH692411A5 CH10597A CH10597A CH692411A5 CH 692411 A5 CH692411 A5 CH 692411A5 CH 10597 A CH10597 A CH 10597A CH 10597 A CH10597 A CH 10597A CH 692411 A5 CH692411 A5 CH 692411A5
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CH
Switzerland
Prior art keywords
sep
essential oil
cel
hydrogenated castor
castor oil
Prior art date
Application number
CH10597A
Other languages
Italian (it)
Inventor
Silvia Bachmann
Original Assignee
Orphea Sa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Orphea Sa filed Critical Orphea Sa
Priority to CH10597A priority Critical patent/CH692411A5/en
Publication of CH692411A5 publication Critical patent/CH692411A5/en

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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A61Q17/02Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings containing insect repellants
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K36/00Medicinal preparations of undetermined constitution containing material from algae, lichens, fungi or plants, or derivatives thereof, e.g. traditional herbal medicines
    • A61K36/18Magnoliophyta (angiosperms)
    • A61K36/185Magnoliopsida (dicotyledons)
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K36/00Medicinal preparations of undetermined constitution containing material from algae, lichens, fungi or plants, or derivatives thereof, e.g. traditional herbal medicines
    • A61K36/18Magnoliophyta (angiosperms)
    • A61K36/185Magnoliopsida (dicotyledons)
    • A61K36/47Euphorbiaceae (Spurge family), e.g. Ricinus (castorbean)
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K36/00Medicinal preparations of undetermined constitution containing material from algae, lichens, fungi or plants, or derivatives thereof, e.g. traditional herbal medicines
    • A61K36/18Magnoliophyta (angiosperms)
    • A61K36/88Liliopsida (monocotyledons)
    • A61K36/899Poaceae or Gramineae (Grass family), e.g. bamboo, corn or sugar cane
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34Alcohols
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34Alcohols
    • A61K8/347Phenols
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8147Homopolymers or copolymers of acids; Metal or ammonium salts thereof, e.g. crotonic acid, (meth)acrylic acid; Compositions of derivatives of such polymers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A61K8/922Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K9/00Medicinal preparations characterised by special physical form
    • A61K9/06Ointments; Bases therefor; Other semi-solid forms, e.g. creams, sticks, gels

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Natural Medicines & Medicinal Plants (AREA)
  • General Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Epidemiology (AREA)
  • Chemical & Material Sciences (AREA)
  • Birds (AREA)
  • Pharmacology & Pharmacy (AREA)
  • Medicinal Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Alternative & Traditional Medicine (AREA)
  • Biotechnology (AREA)
  • Botany (AREA)
  • Medical Informatics (AREA)
  • Microbiology (AREA)
  • Mycology (AREA)
  • Emergency Medicine (AREA)
  • Dermatology (AREA)
  • Plant Pathology (AREA)
  • Pest Control & Pesticides (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Cosmetics (AREA)

Abstract

A gel (I) for protection against insects comprises (by weight) (a) 0.5-2% carbomer, (b) 2-4 % polyoxyethylene hydrogenated castor oil, (c) 30-50% denatured ethanol suitable for cosmetic use, (d) 0.5-2% citronella essential oil, (e) 0.5-2% geranium essential oil, (f) perfume (as required), (g) 0.2-1.5% triethanolamine and (h) water to 100%. An Independent claim is also included for the preparation of (I), comprises: (i) introducing the water (h) into a mixer; (ii) adding (a) under stirring; (iii) homogenizing to give a clear solution; (iv) adding (b) under continued stirring; (v) adding (c), (d) (e) and (f) under stirring; (vi) adding (g); and (vii) mixing thoroughly.

Description

       

  



  La presente invenzione riguarda una formulazione in gel protettiva della persona dalle punture degli insetti (zanzare, vespe, ecc.). Essa è a base di elementi naturali derivanti da piante e fiori quali geranio e citronella. La formula, a base dei sopracitati oli essenziali protegge naturalmente, lasciando la pelle gradevolmente profumata. 



  A differenza dei prodotti insetto-repellenti che hanno finora trovato diffusa applicazione, che si basano su formulazioni insetto-repellenti tradizionali aventi un odore sgradevole e un contenuto più o meno elevato di DEET e la cui efficacia è dovuta quasi esclusivamente ai componenti chimici o farmaceutici, la richiedente ha elaborato il prodotto oggetto della presente domanda basandosi su elementi naturali, quali gli oli essenziali di geranio e citronella. 



  La formula a base di oli essenziali di geranio e citronella, che assicura un efficace effetto repellente, la cui azione è stata scientificamente testata in laboratori indipendenti con criteri rigorosi, lascia la pelle gradevolmente profumata per numerose ore ed è particolarmente indicata per pelli sensibili e per la pelle delicata dei bambini. Il prodotto gel assicura una formulazione che non unge, permette un rapido assorbimento ed è ideale per il viso e per l'applicazione su zone specifiche. 



  Le singole essenze impiegate sono state indicate con il nome sotto il quale esse sono ampiamente conosciute sia dalle ditte produttrici che da tutti gli esperti del ramo. 


 Denominazione materia prima 
 
<tb><TABLE> Columns=3 
<tb>Head Col 3 AL=L: % (wt) 
 tal quale
<tb><SEP>1<SEP>Olio essenziale di geranio
 (incl.: Pelargonium capitatum)<SEP>1,0
<tb><SEP>2<SEP>Olio essenziale di citronella
 (incl.: Cymbopogon nardus)<SEP>1,0
<tb><SEP>3<SEP>Profumo "Citronelle 33.063" Charabot
 (incl.: Parfum/Profumo)<SEP>1,0
<tb><SEP>4<SEP>Alcool etilico denaturato Tipo B
 (incl.: Alcohol denat.)<SEP>40,0
<tb><SEP>5<SEP>Cremophor RH 40
 (incl.: PEG-40 hydrogenated castor oil)<SEP>3,0
<tb><SEP>6<SEP>Ultrez 10
 (incl.: Carbomer)<SEP>1,0
<tb><SEP>7<SEP>Trietanolammina 99%
 (incl.: Triethanolamin)<SEP>1,0
<tb><SEP>8<SEP>Acqua demineralizzata
 (incl.:

   Aqua)<SEP>52,0
<tb><SEP>Totale<SEP>100,0 
<tb></TABLE> 


 Metodo di lavorazione 
 



  - (A) Sciogliere l'utrez 10 nell'acqua demineralizzata, sotto vigorosa agitazione. Prima di proseguire nella lavorazione, assicurarsi che il polimero sia perfettamente disciolto e la soluzione sia priva di grumi. 



  - (B) A parte sciogliere gli oli essenziali e il profumo nell'alcool. In tale soluzione disperdere accuratamente il cremophor. 



  - Unire la soluzione alcoolica B alla soluzione acquosa A sotto agitazione. 



  - Aggiungere la trietanolammina lentamente, mescolando con cura fino ad ottenimento di un gel omogeneo opalino.



  



  The present invention relates to a protective gel formulation of the person from insect bites (mosquitoes, wasps, etc.). It is based on natural elements deriving from plants and flowers such as geranium and lemongrass. The formula, based on the aforementioned essential oils, protects naturally, leaving the skin pleasantly perfumed.



  Unlike the insect-repellent products that have so far found widespread application, which are based on traditional insect-repellent formulations having an unpleasant smell and a more or less high content of DEET and whose effectiveness is due almost exclusively to chemical or pharmaceutical components, the applicant developed the product covered by this application based on natural elements, such as essential oils of geranium and lemongrass.



  The formula based on essential oils of geranium and lemongrass, which ensures an effective repellent effect, the action of which has been scientifically tested in independent laboratories with rigorous criteria, leaves the skin pleasantly perfumed for several hours and is particularly suitable for sensitive skin and for the delicate skin of children. The gel product ensures a non-greasy formulation, allows rapid absorption and is ideal for the face and for application on specific areas.



  The individual essences used have been indicated by the name under which they are widely known both by the manufacturing companies and by all those skilled in the art.


 Raw material name
 
<tb> <TABLE> Columns = 3
<tb> Head Col 3 AL = L:% (wt)
 as it is
<tb> <SEP> 1 <SEP> Geranium essential oil
 (incl .: Pelargonium capitatum) <SEP> 1.0
<tb> <SEP> 2 <SEP> Lemongrass essential oil
 (incl .: Cymbopogon nardus) <SEP> 1.0
<tb> <SEP> 3 <SEP> Perfume "Citronelle 33.063" Charabot
 (incl .: Parfum / Perfume) <SEP> 1.0
<tb> <SEP> 4 <SEP> Denatured ethyl alcohol Type B
 (incl .: Alcohol denat.) <SEP> 40.0
<tb> <SEP> 5 <SEP> Cremophor RH 40
 (incl .: PEG-40 hydrogenated castor oil) <SEP> 3.0
<tb> <SEP> 6 <SEP> Ultrez 10
 (incl .: Carbomer) <SEP> 1.0
<tb> <SEP> 7 <SEP> Triethanolamine 99%
 (incl .: Triethanolamin) <SEP> 1.0
<tb> <SEP> 8 <SEP> Demineralized water
 (Incl .:

   Aqua) <SEP> 52.0
<Tb> <SEP> Total <SEP> 100.0
<Tb> </ TABLE>


 Processing method
 



  - (A) Dissolve utrez 10 in the demineralized water, under vigorous stirring. Before proceeding with the processing, make sure that the polymer is perfectly dissolved and the solution is free of lumps.



  - (B) Apart from dissolving essential oils and perfume in alcohol. In this solution, carefully disperse the cremophor.



  - Add the alcoholic solution B to the aqueous solution A under stirring.



  - Add the triethanolamine slowly, mixing carefully until a homogeneous opal gel is obtained.


    

Claims (3)

1. Prodotto in gel per la protezione da punture di insetti, caratterizzato dalla seguente composizione: <tb><TABLE> Columns=3 <tb>Head Col 3 AL=L: % (in massa) <tb><SEP>Acqua<SEP>q.b. a 100 <tb><SEP>Carbomer<SEP>esempio: Carbopol Ultrez 10 (BF-Goodrich)<SEP>0,5-2 <tb><SEP>Olio di ricino idrogenato polietossilato<SEP>esempio: Cremophor RH 40 (BASF)<CEL AL=L>2-4 <tb><SEP>Alcool etilico denaturato per uso cosmetico<SEP>esempio: Etanolo denaturato tipo B<CEL AL=L>30-50 <tb><SEP>Olio essenziale di Citronella<SEP>esempio: Olio essenziale di Citronella Giava<CEL AL=L>0,5-2 <tb><CEL AL=L>Olio essenziale di Geranio<SEP>esempio: Olio essenziale di Geranio Africa<SEP>0,5-2 <tb><SEP>Profumo<CEL CB=3 AL=L>q.b. <tb><SEP>Trietanolammina<SEP>0,2-1,5 <tb><SEP>Totale<SEP>100 <tb></TABLE>   1. Gel product for the protection from insect bites, characterized by the following composition: <tb> <TABLE> Columns = 3 <tb> Head Col 3 AL = L:% (in mass) <Tb> <SEP> Water <SEP> q.s.. to 100 <tb> <SEP> Carbomer <SEP> example: Carbopol Ultrez 10 (BF-Goodrich) <SEP> 0.5-2 <tb> <SEP> Polyethoxylated hydrogenated castor oil <SEP> example: Cremophor RH 40 (BASF) <CEL AL = L> 2-4 <tb> <SEP> Denatured ethyl alcohol for cosmetic use <SEP> example: Denatured ethanol type B <CEL AL = L> 30-50 <tb> <SEP> Lemongrass essential oil <SEP> example: Java Lemongrass essential oil <CEL AL = L> 0.5-2 <tb> <CEL AL = L> Geranium essential oil <SEP> example: Geranium essential oil Africa <SEP> 0.5-2 <tb> <SEP> Perfume <CEL CB = 3 AL = L> q.b. <Tb> <SEP> Triethanolamine <SEP> 0.2-1.5 <Tb> <SEP> Total <SEP> 100 <Tb> </ TABLE> 2. 2. Prodotto secondo la rivendicazione 1, caratterizzato dalla seguente composizione: <tb><TABLE> Columns=3 <tb>Head Col 3 AL=L: % (in massa) <tb><SEP>Acqua<SEP>q.b. a 100 <tb><SEP>Carbomer<SEP>esempio: Carbopol Ultrez 10 (BF-Goodrich)<SEP>1,0 <tb><SEP>Olio di ricino idrogenato polietossilato<SEP>esempio: Cremophor RH 40 (BASF)<CEL AL=L>3,0 <tb><SEP>Alcool etilico denaturato per uso cosmetico<SEP>esempio: Etanolo denaturato tipo B<CEL AL=L>40 <tb><CEL AL=L>Olio essenziale di Citronella<SEP>esempio: Olio essenziale di Citronella Giava<SEP>1 <tb><SEP>Olio essenziale di Geranio <SEP>esempio: Olio essenziale di Geranio Africa<SEP>1 <tb><SEP>Profumo<SEP>q.b. <tb><CEL AL=L>Trietanolammina<SEP>1 <tb><SEP>Totale<SEP>100 <tb></TABLE>  Product according to claim 1, characterized by the following composition: <tb> <TABLE> Columns = 3 <tb> Head Col 3 AL = L:% (in mass) <Tb> <SEP> Water <SEP> q.s.. to 100 <tb> <SEP> Carbomer <SEP> example: Carbopol Ultrez 10 (BF-Goodrich) <SEP> 1.0 <tb> <SEP> Polyethoxylated hydrogenated castor oil <SEP> example: Cremophor RH 40 (BASF) <CEL AL = L> 3.0 <tb> <SEP> Denatured ethyl alcohol for cosmetic use <SEP> example: Denatured ethanol type B <CEL AL = L> 40 <tb> <CEL AL = L> Lemongrass essential oil <SEP> example: Java Lemongrass essential oil <SEP> 1 <tb> <SEP> Geranium essential oil <SEP> example: Geranium essential oil Africa <SEP> 1 <Tb> <SEP> Perfume <SEP> q.s.. <tb> <CEL AL = L> Triethanolamine <SEP> 1 <Tb> <SEP> Total <SEP> 100 <Tb> </ TABLE> 3. 3. Procedimento per la preparazione del prodotto secondo la rivendicazione 1, caratterizzato dalle seguenti fasi: nel miscelatore principale introdurre l'acqua; sotto agitazione aggiungere il carbomer; miscelare energicamente fino ad ottenere una soluzione omogenea e senza grumi; mantenendo l'agitazione, aggiungere l'olio di ricino idrogenato polietossilato, aggiungere l'alcool etilico; aggiungere l'olio essenziale di citronella, l'olio essenziale di geranio e il profumo, sotto agitazione; aggiungere la trietanolammina e miscelare bene.  Process for preparing the product according to claim 1, characterized by the following steps:    pour water into the main mixer; under stirring add the carbomer; mix vigorously until a homogeneous and lump-free solution is obtained; keeping stirring, add polyethoxylated hydrogenated castor oil, add ethyl alcohol; add lemongrass essential oil, geranium essential oil and perfume, while stirring; add the triethanolamine and mix well.
CH10597A 1997-01-20 1997-01-20 Well tolerated aqueous insect repellent gel for skin protection, containing carbomer, polyoxyethylene hydrogenated castor oil, denatured ethanol and citronella and geranium essential oils CH692411A5 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CH10597A CH692411A5 (en) 1997-01-20 1997-01-20 Well tolerated aqueous insect repellent gel for skin protection, containing carbomer, polyoxyethylene hydrogenated castor oil, denatured ethanol and citronella and geranium essential oils

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH10597A CH692411A5 (en) 1997-01-20 1997-01-20 Well tolerated aqueous insect repellent gel for skin protection, containing carbomer, polyoxyethylene hydrogenated castor oil, denatured ethanol and citronella and geranium essential oils

Publications (1)

Publication Number Publication Date
CH692411A5 true CH692411A5 (en) 2002-06-14

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CH10597A CH692411A5 (en) 1997-01-20 1997-01-20 Well tolerated aqueous insect repellent gel for skin protection, containing carbomer, polyoxyethylene hydrogenated castor oil, denatured ethanol and citronella and geranium essential oils

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102526349A (en) * 2010-12-31 2012-07-04 天津药物研究院 Gel ointment as well as preparation method and application thereof
US8945596B2 (en) 2008-10-20 2015-02-03 Conopco, Inc. Antimicrobial composition
US8992901B2 (en) 2010-05-31 2015-03-31 Conopco, Inc. Skin treatment composition
US9132103B2 (en) 2009-09-24 2015-09-15 Conopco, Inc. Disinfecting agent comprising eugenol, terpineol and thymol
US9408870B2 (en) 2010-12-07 2016-08-09 Conopco, Inc. Oral care composition
US9693941B2 (en) 2011-11-03 2017-07-04 Conopco, Inc. Liquid personal wash composition
EP2758027B1 (en) 2011-07-19 2017-10-25 Coty Inc. Perfume
IT201900009558A1 (en) * 2019-06-20 2020-12-20 Vitalab S R L Cosmetic use of extracts derived from plant cell cultures belonging to the Pelargonium capitatum species and cosmetic compositions containing such extracts

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8945596B2 (en) 2008-10-20 2015-02-03 Conopco, Inc. Antimicrobial composition
US9132103B2 (en) 2009-09-24 2015-09-15 Conopco, Inc. Disinfecting agent comprising eugenol, terpineol and thymol
US8992901B2 (en) 2010-05-31 2015-03-31 Conopco, Inc. Skin treatment composition
US9408870B2 (en) 2010-12-07 2016-08-09 Conopco, Inc. Oral care composition
CN102526349A (en) * 2010-12-31 2012-07-04 天津药物研究院 Gel ointment as well as preparation method and application thereof
CN102526349B (en) * 2010-12-31 2014-04-09 天津药物研究院 Gel ointment as well as preparation method and application thereof
EP2758027B1 (en) 2011-07-19 2017-10-25 Coty Inc. Perfume
US9693941B2 (en) 2011-11-03 2017-07-04 Conopco, Inc. Liquid personal wash composition
IT201900009558A1 (en) * 2019-06-20 2020-12-20 Vitalab S R L Cosmetic use of extracts derived from plant cell cultures belonging to the Pelargonium capitatum species and cosmetic compositions containing such extracts

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