- ICCROM International Centre for the Study of the Preservation and Restoration of Cultural Property
via di san Michele 13
00153 Rome
Italy
Alison Heritage
ICCROM, Collections Unit, Department Member
Research Interests:
It is an unpalatable fact that while objects can deteriorate through lack of care and attention, they can also deteriorate as a result of inappropriate and misguided interventions. This is particularly the case with regard to salt-related... more
It is an unpalatable fact that while objects can deteriorate through lack of care and attention, they can also deteriorate as a result of inappropriate and misguided interventions. This is particularly the case with regard to salt-related deterioration problems. A successful treatment outcome using aqueous salt reduction methods demands an understanding of the transport processes involved as well as detailed information regarding the characteristics and specific situation of the individual object. The use of poultice materials to reduce the salt content of salt deteriorated objects is a long established technique in conservation. However, due to the complex nature of salt problems within historic structures the result of such interventions can be variable and unpredictable. The amount and depth to which salts are mobilised, and where they are transported to, is dependent on the interrelationship between the poultice and the substrate, the drying conditions and also the initial salt distribution. This paper examines the current scientific understanding of salt and moisture transport processes, and the extent to which this knowledge can feed back into the practical arena, to aid the conservator. Moreover, areas where further research is required are identified. In particular, the importance of pre-and post treatment investigations is highlighted, showing how, in combination with knowledge of salt and moisture transport mechanisms, these can give useful indications regarding treatment options. The role of selective salt extraction and the post treatment behaviour of residual salts are discussed.
The crystallization of salts is widely recognized as one of the most significant causes of irreversible damage to many cultural objects such as wall paintings, stone sculptures, and historic buildings. The removal of salts from these... more
The crystallization of salts is widely recognized as one of the most significant causes of irreversible damage to many cultural objects such as wall paintings, stone sculptures, and historic buildings. The removal of salts from these objects is however difficult and often poultices are used. In these methods a wet poultice is applied to the surface of the substrate to be treated and is kept in place for some period of time before being removed. Many studies up to now on poulticing have focused on the salt and moisture transport solely in terms of advection and diffusion. The objective of this study is to demonstrate the potential contribution of osmotic pressure to salt extraction during poulticing treatments. To this end, we have conducted a series of experiments where we have measured the moisture transport during poulticing for some well-defined materials. Here we have used Nuclear Magnetic Resonance (NMR) to measure non-destructively the moisture transport during these experiments. This study shows that osmotic pressure can exert a significant influence on salt extraction by poulticing methods during drying. Importantly, as salt is transported from the substrate and into the poultice, this results in a build-up of osmotic pressure within the poultice decreasing the effective pore-size of the poultice. Therefore, the build-up of osmotic pressure enhances the salt extraction and thus increases the efficiency of the poulticing treatment.
Poultices are often used to extract salts from salt-deteriorated objects, but the results achieved can be highly variable. Currently, poulticing materials and methodologies are selected empirically, but many variables affect the treatment... more
Poultices are often used to extract salts from salt-deteriorated objects, but the results achieved can be highly variable. Currently,
poulticing materials and methodologies are selected empirically, but many variables affect the treatment outcome, so achieving
the ‘best fit’ between available materials, application methods and substrate characteristics is somewhat arbitrary. This research,
undertaken during the EC Desalination project (FP6 022714), investigated whether the extraction efficiency of drying poultices
can be optimized by adjusting the poultice pore-size distribution to suit that of the substrate. Different substrate/poultice
combinations of varying pore-size distributions (determined by nuclear magnetic resonance and mercury intrusion porosimetry)
were selected for extraction efficiency tests. The results demonstrated that a prerequisite for efficient salt extraction by a drying
poultice is that it has smaller pores than the substrate. However, the residual salt distribution after treatment was independent of
the experimental factors tested. Thus, while manipulation of the poultice pore-size distribution can enhance salt extraction, this
does not govern the location of residual salts. This study demonstrates that poultices should be adapted to suit the characteristics of
the object undergoing treatment. However, the uncontrolled residual salt distribution and potential re-emergence of salt problems
mean that the effectiveness of poulticing treatments requires long-term assessment.
poulticing materials and methodologies are selected empirically, but many variables affect the treatment outcome, so achieving
the ‘best fit’ between available materials, application methods and substrate characteristics is somewhat arbitrary. This research,
undertaken during the EC Desalination project (FP6 022714), investigated whether the extraction efficiency of drying poultices
can be optimized by adjusting the poultice pore-size distribution to suit that of the substrate. Different substrate/poultice
combinations of varying pore-size distributions (determined by nuclear magnetic resonance and mercury intrusion porosimetry)
were selected for extraction efficiency tests. The results demonstrated that a prerequisite for efficient salt extraction by a drying
poultice is that it has smaller pores than the substrate. However, the residual salt distribution after treatment was independent of
the experimental factors tested. Thus, while manipulation of the poultice pore-size distribution can enhance salt extraction, this
does not govern the location of residual salts. This study demonstrates that poultices should be adapted to suit the characteristics of
the object undergoing treatment. However, the uncontrolled residual salt distribution and potential re-emergence of salt problems
mean that the effectiveness of poulticing treatments requires long-term assessment.