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Alison Heritage
  • ICCROM International Centre for the Study of the Preservation and Restoration of Cultural Property
    via di san Michele 13
    00153  Rome
    Italy

Alison Heritage

ICCROM, Collections Unit, Department Member
This article presents the first non destructive measurements of salt ions transport through fired-clay brick during electrokinetic desalination using nuclear magnetic resonance technique. The effect of the strength of an applied electric... more
This article presents the first non destructive measurements of salt ions transport through fired-clay brick during electrokinetic desalination using nuclear magnetic resonance technique. The effect of the strength of an applied electric field on the migration of salt ions is examined by varying the electrical potential gradients from 0.75–2 V cm-1 across the specimens. The measurements show that for electrokinetic to exceed ion transport by diffusion a minimum level of applied voltage is necessary. Below this threshold salt transport by diffusion is dominant over electromigration. The effect of advec-tion on the salt transport is studied by introducing a hydraulic gradient across the specimen. The results show that advection is a major transport process in the materials studied. To assess the relative magnitude of the various active transport processes during electrokinetic desalination, a scale analysis on the basis of dimensionless numbers is presented. The value of these numbers determines which transport mechanism will dominate the desalination process in a given sample length and time scale.
It is an unpalatable fact that while objects can deteriorate through lack of care and attention, they can also deteriorate as a result of inappropriate and misguided interventions. This is particularly the case with regard to salt-related... more
It is an unpalatable fact that while objects can deteriorate through lack of care and attention, they can also deteriorate as a result of inappropriate and misguided interventions. This is particularly the case with regard to salt-related deterioration problems. A successful treatment outcome using aqueous salt reduction methods demands an understanding of the transport processes involved as well as detailed information regarding the characteristics and specific situation of the individual object. The use of poultice materials to reduce the salt content of salt deteriorated objects is a long established technique in conservation. However, due to the complex nature of salt problems within historic structures the result of such interventions can be variable and unpredictable. The amount and depth to which salts are mobilised, and where they are transported to, is dependent on the interrelationship between the poultice and the substrate, the drying conditions and also the initial salt distribution. This paper examines the current scientific understanding of salt and moisture transport processes, and the extent to which this knowledge can feed back into the practical arena, to aid the conservator. Moreover, areas where further research is required are identified. In particular, the importance of pre-and post treatment investigations is highlighted, showing how, in combination with knowledge of salt and moisture transport mechanisms, these can give useful indications regarding treatment options. The role of selective salt extraction and the post treatment behaviour of residual salts are discussed.
The crystallization of salts is widely recognized as one of the most significant causes of irreversible damage to many cultural objects such as wall paintings, stone sculptures, and historic buildings. The removal of salts from these... more
The crystallization of salts is widely recognized as one of the most significant causes of irreversible damage to many cultural objects such as wall paintings, stone sculptures, and historic buildings. The removal of salts from these objects is however difficult and often poultices are used. In these methods a wet poultice is applied to the surface of the substrate to be treated and is kept in place for some period of time before being removed. Many studies up to now on poulticing have focused on the salt and moisture transport solely in terms of advection and diffusion. The objective of this study is to demonstrate the potential contribution of osmotic pressure to salt extraction during poulticing treatments. To this end, we have conducted a series of experiments where we have measured the moisture transport during poulticing for some well-defined materials. Here we have used Nuclear Magnetic Resonance (NMR) to measure non-destructively the moisture transport during these experiments. This study shows that osmotic pressure can exert a significant influence on salt extraction by poulticing methods during drying. Importantly, as salt is transported from the substrate and into the poultice, this results in a build-up of osmotic pressure within the poultice decreasing the effective pore-size of the poultice. Therefore, the build-up of osmotic pressure enhances the salt extraction and thus increases the efficiency of the poulticing treatment.
Poultices are often used to extract salts from salt-deteriorated objects, but the results achieved can be highly variable. Currently, poulticing materials and methodologies are selected empirically, but many variables affect the treatment... more
Poultices are often used to extract salts from salt-deteriorated objects, but the results achieved can be highly variable. Currently,
poulticing materials and methodologies are selected empirically, but many variables affect the treatment outcome, so achieving
the ‘best fit’ between available materials, application methods and substrate characteristics is somewhat arbitrary. This research,
undertaken during the EC Desalination project (FP6 022714), investigated whether the extraction efficiency of drying poultices
can be optimized by adjusting the poultice pore-size distribution to suit that of the substrate. Different substrate/poultice
combinations of varying pore-size distributions (determined by nuclear magnetic resonance and mercury intrusion porosimetry)
were selected for extraction efficiency tests. The results demonstrated that a prerequisite for efficient salt extraction by a drying
poultice is that it has smaller pores than the substrate. However, the residual salt distribution after treatment was independent of
the experimental factors tested. Thus, while manipulation of the poultice pore-size distribution can enhance salt extraction, this
does not govern the location of residual salts. This study demonstrates that poultices should be adapted to suit the characteristics of
the object undergoing treatment. However, the uncontrolled residual salt distribution and potential re-emergence of salt problems
mean that the effectiveness of poulticing treatments requires long-term assessment.
This paper examines some of the current science policy paradigms set at international level to promote open science and participatory research, and discusses how key factors necessary for successful collaboration can usefully contribute... more
This paper examines some of the current science policy paradigms set at international level to promote open science and participatory research, and discusses how key factors necessary for successful collaboration can usefully contribute to the training of future conservation professionals through group work and research-based learning programmes.
The ICCROM Forum 2013 on Conservation Science resulted in a series of recommendations for improving the relevance and impact of science within cultural heritage conservation. These recommendations are outlined in this paper. Central to... more
The ICCROM Forum 2013 on Conservation Science resulted in a series of recommendations for improving the relevance and impact of science within cultural heritage conservation. These recommendations are outlined in this paper. Central to the Forum recommendations is the responsibility of conservation science to provide benefit through research and innovation. This relies on shared strategic vision and good governance, to identify priority needs and align efforts accordingly. To enhance the effectiveness of conservation science research, it is imperative to adopt an approach based on needs assessment, collaboration, and sharing. However, to establish whether desired goals are being met, systematic assessment of what is delivered and how it is used is required. Evaluation tools provide a structured way to identify needs and to measure results, offering a basis for learning and improvement. A new initiative is outlined, launched by ICCROM in follow-up to the Forum, to develop a common framework for needs and outcome assessment for heritage conservation science. To achieve this will require participation and support at multiple levels, and collaboration is called for to continue and sustain this effort.
This paper presents preliminary results from the ICCROM Forum on Conservation Science, which took place in October 2013. This initiative was organised by ICCROM in partnership with 15 conservation research and training institutions... more
This paper presents preliminary results from the
ICCROM Forum on Conservation Science, which
took place in October 2013. This initiative was organised
by ICCROM in partnership with 15 conservation
research and training institutions spanning
Europe, North America, Latin America and Asia.
Background research undertaken before the Forum
examined research trends, strategy development,
information dissemination, education and training,
job opportunities and the impacts of science
within conservation. These surveys revealed stark
inequalities between countries and regions in regard
to knowledge production and access to scientific
information and services, limited research
opportunities for non-institutional players and a
shortage of job openings for young conservation
scientists. In its conclusions, the Forum stressed
the need for the sector to embrace all relevant sciences,
to place greater emphasis on wider societal
issues and to undertake strategy development.
Building on the Forum experience, ICCROM will
explore options for the regular collection of indicators
for conservation science.
Research Interests:
ABSTRACTCellulose poultices are frequently used in stone and wall painting conservation for the purposes of soluble salt extraction, consolidation and cleaning. They have the reputation of being easy and pleasant to work with, have a... more
ABSTRACTCellulose poultices are frequently used in stone and wall painting conservation for the purposes of soluble salt extraction, consolidation and cleaning. They have the reputation of being easy and pleasant to work with, have a neutral pH, high water absorption and plasticity, exhibit good conformance and adhesion to the substrate, and in most cases leave minimal residues after clearance. The cellulosic materials from which they are composed range from cotton wool, blotting paper or newspaper, to cellulose powders, the latter now by far the most common form of cellulose used today by conservators. Drawbacks of these products include poor water retention when applied to vertical surfaces, a tendency to redistribute salts further into the object substrate, and poor long-term treatment effectiveness for salt extraction. Hence cellulose poultices are used frequently due to good working properties, but apparently are in some situations not very effective. In this paper, existing knowledge of these poultices is outlined, followed by investigations undertaken to fill some of the knowledge gaps. Investigations include characterization of poultice properties such as pore size distribution and workability, and of moisture transport processes within poultice/substrate systems including moisture penetration depth, moisture distribution, and poultice shrinkage during drying. Cellulose powder products known under the trade name Arbocel®, extensively tested and used in conservation over several decades, were a particular focus. Resulting guidelines include counter-intuitive measures such as (when used for salt extraction purposes) the use of thinner poultices to reduce drying shrinkage and salt redistribution further into the substrate. The relatively uniform pore size distribution (around 10 μm) of Arbocel® poultices makes them more appropriate for salt extraction on substrates with a medium-coarse pore size (i.e. 15 μm and above), while on fine porous substrates (10 μm and below), the extraction will not be as efficient.