Content deleted Content added
m cat |
|||
Line 37:
:2 Na + 2 C<sub>5</sub>H<sub>6</sub> → 2 NaC<sub>5</sub>H<sub>5</sub> + [[Hydrogen|H<sub>2</sub>]]
The use of "sodium sand", a fine dispersion of sodium prepared by melting sodium in refluxing [[xylene]] and rapidly stirring, is traditional.<ref name = ferrocene>{{OrgSynth | title = Ferrocene | author = [[Geoffrey Wilkinson|Wilkinson, Geoffrey]] | collvol = 4 | collvolpages = 473 | year = 1963 | prep = cv4p0473}}</ref><ref>{{OrgSynth | author = Partridge, John J.; Chadha, Naresh K.; Uskokovic, Milan R. | title = An asymmetric hydroboration of 5-substituted cyclopentadienes: synthesis of methyl (1''R'',5''R'')-5-hydroxy-2-cyclopentene-1-acetate | collvol = 7 | collvolpages = 339 | prep = cv7p0339 | year = 1990}}</ref> [[Sodium hydride]] is a convenient base:<ref>Girolami, G. S.; Rauchfuss, T. B. and Angelici, R. J., Synthesis and Technique in Inorganic Chemistry, University Science Books: Mill Valley, CA, 1999.ISBN
:NaH + C<sub>5</sub>H<sub>6</sub> → NaC<sub>5</sub>H<sub>5</sub> + H<sub>2</sub>
Line 55:
[[Category:Sodium compounds]]
[[Category:Organometallic compounds]]
[[Category:Cyclopentadienyl complexes]]
|