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The study of diffuse soft X-ray background

The cosmic X-ray background was discovered at the dawn of the X-ray astronomy: during the first successful rocket flight launched to study the X-ray emission from the Moon, the presence of a residual diffuse emission was also “serendipitously” revealed. In the intervening decades, observations with improving angular and spectral resolution have enhanced our understanding of the components that make up this background. Above 1 keV, the emission is highly isotropic on large angular scales, has extragalactic origin, and about ∼80 percent has been resolved into discrete sources Mushotzky et al. 2000, Hasinger et al. 1998). Our current interpretation of the diffuse X-ray emission below 1 keV uses a combination of 5 components, solar wind charge exchange, Local Bubble, Galactic halo, intergalactic gas, and unresolved point sources. Resolving the different components is made particularly difficult by the similar spectral emission of most components, X-ray lines of heavily ionized metals, which are poorly resolved by the energy resolution of CCD cameras onboard current X-ray satellites with typical observing times. The goal of this investigation is to assess the integral emission of the major components of the diffuse Soft X-Ray Background. In the first part of my project, I analyzed the shadow observations performed with XMM-Newton and Suzaku X-ray observatories. Shadow observations offer a tool to separate the fore ground component, due to the Local Bubble and, possibly, charge exchange within the solar system, from the background component, due primarily to the Galactic Halo and unidentified point sources. In the second part of my project, I studied the contribution of unresolved point sources and intergalactic medium to the diffuse Soft X-ray Background.

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Chasing mu

Conducting and semiconducting, pi-conjugated polymers are promising materials for micro- and nano-optoelectronic applications because of their widely tunable physical, electrical, and optical properties. These polymers have been used to fabricate a number of electronic devices including field-effect transistors, light-emitting diodes, and photovoltaic cells. However, widespread commercial application of these devices has yet to be realized, due in part to poor electronic transport characteristics and device degradation. Nanostructuring of conjugated polymers by various methods has demonstrated marked improvements in molecular ordering and electronic transport. In this research, nanoscale, tubular structures of semiconducting polymers fabricated by template wetting nanofabrication procedures are explored. In particular, confinement-induced effects on the electronic carrier transport property mobility, mu, were investigated for both highly ordered and amorphous polymers. Analysis of space-charge-limited currents provided the key means of monitoring transport characteristics and molecular order. The effects of chemical filtration, nanotube diameter, solvent selection, and temperature are examined in detail.

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Disjoint cycles and tree packings in graphs

This dissertation is a contribution to two classical areas of graph theory, partitioning the vertex set of a graph into disjoint cycles, and packing trees into graphs. In addition to the original results which appear in two papers, we provide a historical background of each topic and a unifying perspective. Chapter 1 contains historical background going back to Euler, Hamilton, and Cayley who can be considered some of the fathers of these topics. Chapter 2 includes two surveys that show the development of both topics. These surveys contain preliminary results needed in the foregoing. Chapter 3 contains our contribution to the area of disjoint cycles. It is motivated by the following conjecture of El-Zahar. If G is a graph of order n = n1 + n2 + ··· + nk with n2 ≥ 3 1 ≤ i ≤ k) and the minimum degree of G is at least n1/2+ n2/2+˙˙˙+ nk/2 , then G contains k independent cycles of lengths n1, n2, …, nk, respectively. Several previous results toward the resolution of this conjecture have been attained by Dirac, Corradi and Hajnal, and Wang. Our contribution settles the case where n 1 = n2 = ··· = ns =3 1 ≤ s ≤ k) and ns+1 = ns +2 = ··· = nk = 5. Chapter 4 contains our contribution to the tree packing problem which is motivated in part by the observation that trees with large maximum degree are the major obstacle for achieving the packing. Continuing previous works of Bollabas, Wang, and Sauer and Spencer we prove that two trees T1 and T2 of order n, with Delta = max {Delta T1), Delta T2)}, can be packed into a graph with restrained maximum degree. In particular, we show there is a packing a such that Delta T1 ∪ sigmaT2)) ≤ Delta + 2.

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Connectivity and characteristic polynomials of binary matroids

In this dissertation we investigate two main topics: minor-minimally 3-connected matroids and characteristic polynomials. Chapter 1 provides a survey of basic concepts from matroid theory that will be referenced in later chapters. The remainder of this dissertation includes the main results, their proofs, as well as motivation of these results. A 3-connected matroid M is minor-minimally 3-connected if, for every e ∈ EM), either M\e or M/e is not 3-connected. In Chapter 2, we review several theorems concerning minor-minimally 3-connected matroids. We also consider a conjecture of Wagner, which is the motivation of our research in this area. We provide a counterexample to Wagners conjecture in this chapter. In Chapter 3 we introduce and prove our main result concerning minor-minimally 3-connected binary matroids. This is a chain-type theorem that offers a characterization of minor-minimally 3-connected binary matroids. As a consequence, one can generate all minor-minimally 3-connected binary matroids starting from MK4 ), the graphic matroid of the complete graph with four vertices, the Fano matroid F7, and its dual. The characteristic polynomial of a rank r matroid M with ground set E is defined as cM,x= X⊆E-1 Xxr-r X. The characteristic polynomial PG x) of a graphic matroid MG) is related to the chromatic polynomial of G by the equation PGx=xw Gc MG,x where oG) is the number of components of G. In Chapter 4, we present existing results concerning these polynomials, and we prove a broken-circuit theorem for matroids. In Chapter 5, we give new upper and lower bounds for the coefficients of the characteristic polynomial of simple binary matroids. New bounds for the coefficients of the flow polynomials of graphs can be obtained as a direct consequence.

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Propagation of plate acoustic waves in Z-cut lithium niobate: Single crystal and periodically poled wafers

The dispersion characteristics of plate acoustic waves PAW) that propagate in the X direction of a Z-cut single crystal and periodically poled lithium niobate PPLN) wafers are investigated theoretically and experimentally. The numerical calculations are performed with the aid of Finite Element method FEM) and the method of partial waves. In the series of experiments, the vertical acoustical displacement and electric potential are measured off the plate surface. The dispersion relations between the frequency f and the wavenumber beta are calculated for the first eight acoustic modes by applying the discrete Fourier transform DFT) to the calculated and measured displacement. The phase and group velocity dispersion relations are calculated from the wavenumber dispersion betaf). The dispersion curves of PAW that propagate in a PPLN crystal are compared to the single crystal case. An increase in the cutoff frequency of some modes propagating in PPLN plate is found. The dispersion curves of PAW in PPLN wafer show stop bands at certain values of f. The stop band occurs where the wavelength of a propagating mode is equal to the period of ferroelectric domains. The group velocity of acoustic modes decreases to zero at stop bands. The piezoelectric coupling coefficient K2) is calculated for the first eight PAW modes in a lithium niobate LN) plate. It is shown to be higher than the K2 of surface waves. An ultrasonic delay line that operates on the modes with higher K2 is numerically simulated, fabricated, and tested. The dispersion curves for PAW in periodically corrugated lithium niobate wafer are calculated. A complete band gap in the dispersion curves of three zero order modes occurs at the frequencies where the stop bands of zero order modes coincide.

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A theoretical study of methanol oxidation mechanisms by methanol dehydrogenase enzymes for fuel cell applications

Enzymes are considered for electrochemical generation of power in fuel cells. Methanol dehydrogenase MDH) is one such enzyme, which has been used as an anodic catalyst for a methanol-fed biofuel cell producing enough power for small electronic device applications. In practice, however, there are power output limitations associated with this MDH fuel cell, which may potentially be eliminated or reduced if the reactivity of this enzyme during the oxidation of methanol at the molecular level is clearly understood. Two mechanisms for the methanol oxidation process by MDH have been proposed in the literature, Addition-Elimination A-E) and Hydride Transfer H-T), but no agreement has been reached about what mechanism actually operates in reality. Also, it was suggested that ion-modified MDH, particularly Ba 2+-MDH enzyme, is more active towards oxidation of methanol than Ca 2+-MDH from experimental kinetic observations. In this dissertation, MDH active site models of varying sizes were tested for the A-E and H-T methanol oxidation in the presence of both Ca2+ and Ba2+. Potential energy surfaces for the reactions were calculated, and the feasibility of the suggested reaction mechanisms was judged by comparison with available experimental free energy barriers. By systematically increasing the size of the models, deeper insight into the details of the reactions was obtained, and the role of the various active site residues was also analyzed. Comparison of free energy barriers calculated for the rate-determining steps in this work for the A-E and H-T oxidation mechanisms with experimental Gibbs energy of activation by Ca2+-MDH showed that these two mechanisms may not be correctly proposed in the literature. Also, the reduction of barriers for the rate-determining steps in the presence of Ba2+ for A-E and H-T obtained with the best MDH active site model tested here is almost twice as much the experimental free energy reduction with Ba 2+-MDH for methanol oxidation. A modified first step of original H-T resulted in a newly proposed two-step H-T oxidation mechanism, where the barrier for the formation of final product, formaldehyde, during the first step is very much comparable 11.4 kcal/mol) to the experimental Gibbs energy of activation 8.5 kcal/mol). In the case of Ba2+ presence during this new mechanism, the free energy barrier is 6.2 kcal/mol, which is comparable to free energy of activation for oxidation of methanol by Ba2+-MDH 3.5 kcal/mol). The second and final step involving proton transfer in this Two-step H-T was observed to be mediated by a water molecule in the presence of both ions. Moreover, DFT-MD investigations on the reactant complex and necessary intermediates associated with all mechanisms also lead us to the conclusion that oxidation of methanol by MDH has a greater probability of proceeding through the two-step hydride transfer mechanism compared to proposed A-E and H-T.

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A physical approach to boundary conditions for the characterization of one-dimensional nanomaterials

The production of sub-micron structures has created a need for techniques to characterize these structures. This is especially true since many of the materials composing these structures do not behave as would be predicted by traditional meso-scale equations. This paper considers both experimental and theoretical aspects of the three-point bending method for measuring the elastic modulus of 1-D nanostructures such as wires, tubes, and belts. Three-point bending tests were performed using an atomic force microscope (AFM) on silica nanowires suspended over micro-channels. Detailed consideration was given to AFM calibration, measurement uncertainty, and the importance of the boundary conditions existing where the wires are anchored to the test structure. Correct representation of the boundary conditions is critical for the use of models with the observed data to estimate the elastic modulus. The standard fixed and simple beam models have been used exclusively for estimating the elastic modulus, despite their unrealistic representation of boundary conditions. The Winkler model is applied here to represent an elastic bond between the nanowires and the polymer film anchoring them to the test structure. The application of this model requires measurement of the elastic modulus of the polymer, which was accomplished in this study via indentation testing with an AFM probe. The results clearly indicate that the silica nanowires in this study, with diameters between 50 and 130 nm, have an apparent elastic modulus greater than bulk. The results suggest that the apparent elastic modulus increases with smaller diameters in a way consistent with predictions made through the consideration of energy stored in the nanowires in the form of surface tension.

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On the independence polynomials of k-tree related and well-covered graphs

Independence Polynomials have been introduced several times, independently and with various names [6, 8, 9], beginning in the early 1980s. Applications have been found in Molecular Chemistry and Statistical Physics. The purposes of this dissertation include the derivation of tight upper and lower bounds for the coefficients of the independence polynomial of a k-tree: n-ks-1 s ≤fsT kn≤ n-k s where Tkn is a k-tree with n vertices and fs is the coefficient of xs in the independence polynomial of Tkn . All instances of equality at the upper and lower bounds are determined. This result generalizes a theorem of Wingard [21] corresponding to k = 1. A second focus of this dissertation is the exact determination of the independence polynomials in several classes of k-trees, including k, n)-paths, k, n)-stars, and k, n)-spirals, and in some graphs which are closely related to k-trees. These include k, n)-cycles and k, n)-wheels. A third focus is the determination of the independence polynomial in a certain class of well-covered graphs. These graphs are described by a construction in Chapter 4 and their independence polynomials are computed using a very general theorem. In cases where the polynomial can be determined in closed form and its coefficients determined separately, the independence polynomial is used to generate some new combinatorial identities. Finally, the independence structure of the line graph of a 2 x n lattice is considered. While the exact determination of the polynomial remains an open question, the fibonacci number of this graph, that is, the sum of the coefficients of its polynomial, is determined precisely for all n. At the end of this dissertation, some further related research problems are proposed.

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Carrier-envelope phase stabilization of grating-based chirped-pulse amplifiers

In this research, the carrier-envelope phase CE phase) evolution of the pulse train from a Kerr-lens mode-locked chirped-mirror dispersion compensated Ti:Sapphire laser oscillator was stabilized. The offset frequency corresponding to the rate of change of the CE phase was obtained by spectrally broadening the oscillator pulses in a photonic crystal fiber and interfering the f and 2f components. An offset frequency linewidth of 100 mHz was obtained and could be locked over several hours. The effect of path length drift in the interferometer used for CE phase stabilization of the laser oscillator was investigated. By stabilizing the path length drift, the interferometer noise was reduced by several orders of magnitude. The CE phase drift through a grating-based chirped-pulse multi-pass amplifier was investigated. Varying the grating separation by 1microm in the stretcher was found to cause a shift of 3.7 +/-1.2 rad of the CE phase. The CE phase could be stabilized to within 160 mrad rms error by feedback controlling the grating separation. By locking the path length in the f-to-2f interferometer used to stabilize the CE phase of the oscillator pulses, the fast >3 Hz) CE phase drift of the amplified laser pulses was reduced from 79 to 48 mrad. It was also found that the CE phase could be shifted and set to any value within a 2pi range by changing the grating separation. Also, the CE phase could be continuously modulated within a 2pi range while maintaining a relative phase error of 171 mrad. The CE phase shift of a grating-based compressor was found to be stabilized to 230 mrad rms. The effect of laser power fluctuation on the CE phase measurement was also investigated. It was found that a 1% fluctuation of the laser energy caused a 160 mrad error in the CE phase measurement. A two-step model is proposed to explain the phase-energy coupling in the CE phase measurement. The model explains the experimentally observed dependence of the group delay between the f and 2f pulses on the laser energy. Few-cycle pulses were CE phase stabilized to 134 mrad rms and were used to perform above-threshold ionization and high harmonic generation.

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Weyl filtration dimension and submodule structures for B2

Let G be a connected and simply connected semisimple algebraic group over an algebraically closed field of positive prime characteristic. Let L(lambda) and Delta(lambda) be the simple and induced finite dimensional rational G-modules with p-singular dominant highest weight lambda. In this thesis, the concept of Weyl filtration dimension of a finite dimensional rational G-module is studied for some highest weight modules with p-singular highest weights inside the p 2-alcove when G is of type B 2. In Chapter 4, intertwining morphisms, a diagonal G-module morphism and tilting modules are used to compute the Weyl filtration dimension of L(lambda) with lambda p-singular and inside the p2 -alcove. It is shown that the Weyl filtration dimension of L(lambda) coincides with the Weyl filtration dimension of Delta(lambda) for almost all (all but one of the 6 facet types) p-singular weights inside the p2-alcove. In Chapter 5 we study some submodule structures of Weyl (and there translations), Vogan, and tilting modules with both p-regular and p-singular highest weights. Most results are for the p2-alcove only although some concepts used are alcove independent.

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